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- Given that the equivalence point volume from the second derivative plot is 7.3429, how many grams of salicylic acid (138.121 g/mol) was synthesized? To determine the yield of the hydrolysis reaction, potentiometric titration was done. NaOH was used as the titrant, and three trials of standardization with KHP yields a titrant concentration of 0.0427 M.Solve the following problem: Calamine, which is used to relieve skin irritations, is a mixture of zinc and iron oxides. A 1.056 g sample of dry calamine was dissolved in acid and diluted to 250.0 mL. Potassium fluoride was added to a 10.00 mL aliquot of the diluted solution to mask the iron. After adjusting the pH, the Zn2+ consumed 38.37 mL of EDTA 0.01133 M. A second aliquot of 50.00 mL was buffered and titrated with 2.30 mL of a solution of ZnY2- 0.002647 M: Fe3+ + ZnY2- → FeY- + Zn2+ Calculate the percentages of ZnO and Fe2O3 in the sample.For µ=0.1, the activity coefficient (gamma) of M2+ is 0.41 while gamma of X- is 0.75. Calculate how many micrograms of MX2 dissolve in 324 mL of 0.10 M NaX solution. The molar mass of MX2 is 201 g/mol, and its Ksp is 3.8 x 10-9. Note that NaX is a salt of X-, an ion that participates in the equilibrium that applies to the solubility of MX2. a. 110 µg b. 27 µg c. 9.7 µg d. 44 µg e. 1000 µg
- A Fajans titration of a 0.7908-g sample required 45.32 mL of 0.1046 M AgNO3 . Express the results of this analysis in terms of the percentage of BaCl2 * H2O. (Use a MW value in 4 decimal places)In an unprecedented initiative, the professor chose you to carry out the determination of a special sample in order to verify the inherent indication system. For that, an aliquot of 25.00 mL of a solution containing Fe(III) salts was titrated with EDTA 0.00982 mol/L, using potassium thiocyanate as indicator. In this case, you have found the volume of 31.10 mL of titrant to End Point. Based on the information given in the table, choose the option that best describes/explains the process linked to the indication system of the Final Point of the degree: (a) The indication of the system will be given by the disappearance of the reddish coloration, due to the displacement reaction: Fe(III) complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate. (b) The indication of the system will be given by the appearance of a reddish color, in function of the displacement reaction: Fe(III) complex with thiocyanate is formed in detriment of the Fe(III) complex with EDTA. (c) The…A 0.1220 g vitamin C tablet was dissolves in acid. A 25.00 ml aliquot of 0.01740 M KIO3 was added along with excess KI. The resulting solution was titrated with 0.07210 M Na2S2O3, requiring 21.44 mL to reach the endpoint. calculate percent by weight of ascorbic acid in the tablet.
- Which of the following is a good description of a standard solution as a titrant? a) selectively reactive with the analyte b) only reacts with the matrix c) oxidize when exposed to air d) reacts very slowly but completelyCalculate NaCl equivalent of a 1% solution of pilocarpine nitrate. Pilocarpine nitrate has molecular weight of 271 and i of 1.8 (Give clear handwritten answer)A 0.512 g sample of CaCO3 is dissolved in 12 M HCl and the mixture is diluted to 250 mL. A small amount of MgCl2 solution is added to a 25 mL aliquot of the solution., and the mixture is titrated with (ethylenediaminetetraacetic acid) EDTA to the Eriachrome Black T (with MgCl2 is used as indicator) end point. The mixed solution requires 28.55 mL of the EDTA solution to reach the end point. A similar amount of MgCl2 solution requires 2.60 mL to reach the endpoint. A 100-mL sample of hard water is titrated with 22.4 mL of the EDTA solution created above. The same amount of MgCl2 is added as previously and the total volume of EDTA solution required is 22.44 mL. a) Assume all of the Ca2+ in the water comes from CaCO3. How many moles of CaCO3 are in 1 L of water? How many grams of CaCO3 are in 1 L of water? c) If 1 ppm CaCO3 = 1 mg/liter, what is the water hardness in ppm CaCO3 ?
- A 0.512 g sample of CaCO3 is dissolved in 12 M HCl and the mixture is diluted to 250 mL. A small amount of MgCl2 solution is added to a 25 mL aliquot of the solution., and the mixture is titrated with (ethylenediaminetetraacetic acid) EDTA to the Eriachrome Black T (with MgCl2 is used as indicator) end point. The mixed solution requires 28.55 mL of the EDTA solution to reach the end point. A similar amount of MgCl2 solution requires 2.60 mL to reach the endpoint. A 100-mL sample of hard water is titrated with 22.4 mL of the EDTA solution created above. The same amount of MgCl2 is added as previously and the total volume of EDTA solution required is 22.44 mL. a) What volume of EDTA is used in titrating the Ca2+ in the hard water? b) How many moles of EDTA are there in that volume? c) How many moles of Ca2+ are in 100 mL of water?A 0.512 g sample of CaCO3 is dissolved in 12 M HCl and the mixture is diluted to 250 mL. A small amount of MgCl2 solution is added to a 25 mL aliquot of the solution., and the mixture is titrated with (ethylenediaminetetraacetic acid) EDTA to the Eriachrome Black T (with MgCl2 is used as indicator) end point. The mixed solution requires 28.55 mL of the EDTA solution to reach the end point. A similar amount of MgCl2 solution requires 2.60 mL to reach the endpoint. A 100-mL sample of hard water is titrated with 22.4 mL of the EDTA solution created above. The same amount of MgCl2 is added as previously and the total volume of EDTA solution required is 22.44 mL. How many moles of Ca2+ are in 100 mL of water?A 0.512 g sample of CaCO3 is dissolved in 12 M HCl and the mixture is diluted to 250 mL. A small amount of MgCl2 solution is added to a 25 mL aliquot of the solution., and the mixture is titrated with (ethylenediaminetetraacetic acid) EDTA to the Eriachrome Black T (with MgCl2 is used as indicator) end point. The mixed solution requires 28.55 mL of the EDTA solution to reach the end point. A similar amount of MgCl2 solution requires 2.60 mL to reach the endpoint. How many milliliters of EDTA are needed to titrate the Ca2+ ion in the sample? How many moles of EDTA are there in the volume calculated for the question above? What is the molarity of the EDTA solution?