Direct Cross-Dehydrogenative-Coupling (CDC) between Benzyl Ethers and Simple Ketones: DDQ O-RI 100°C DDQ(0.25mmol) 100°C, N2. 2.5h 1a 13b 0.2mmol 0.6mmol isolated yield 50% 16c 16d
Q: When tert-pentyl chloride (2-chloro-2- methylbutane) undergoes solvolysis in aqueous ethanol at room…
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Q: When tert-pentyl chloride (2-chloro-2- methylbutane) undergoes solvolysis in aqueous ethanol at room…
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Q: of 8 -+ Automatic Zoomn View as To Which one of the following benzene analogs provides neither ortho…
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A: 2 mole of HCl 2 mole of (ch3)2CuLi
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Q: Name: 1) Show the role of each ether solvent (diethyl ether, THF and crown ether) in reactions by…
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Q: Below are two potential methods for preparing the same ether, but only one of them is successful.…
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Q: Treatment of 1,2-dimethylcyclopentene with OsO4, followed by aqueous NaHSO3, produces which of the…
A: -> when OsO4/NaHSO3 added to alkene then syn diol product is formed .
Q: Which sequence of reactions could you use to prepare 2,2-dimethylpentane from 1-pentyne (shown)?…
A: Ans
Q: (b) Each of the following alcohols has been subjected to acid-catalyzed dehydration and yields a…
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Q: Which of the alcohols listed below would you expect to react most rapidly with PBr3?…
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A: Given: Although benzene itself absorbs at 128 ppm in its 13C NMR spectrum, the carbons of…
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Q: A compound containing one functional group has IR absorption bands at 3300 cm1 (strong, sharp) and…
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Q: Which of the following alcohols reacts fastest with HBr to give the corresponding alkyl bromide…
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A: The solution of the question is given below:
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Q: (1) 4-Phenyl Phenol (2) KOH in ethanol (1M) (3) Benzyl chloride (4) 4-benzyloxy biphenyl (1) (2)…
A: Well, we know in williamson ether synthesis, the recation is 1:1. 1mole of reactant react to form…
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Q: The following ethers can, in principle, be synthesized by two different combinations of haloalkane…
A: The ethers can be synthesized into two different combinations of halo alkane or halo cycloalkane and…
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Q: CH3 (CH3);CONA H,CH,C- -CH(CH3)2 (CH3);COH, 55°C
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Q: Using your reaction roadmap as a guide, show how to convert cyclohexane into hexane- dial. Show all…
A: Given:
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A: The reaction taking place is given as,
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- Qa 18. Bromination of 5a-cholestan-3-one occurs at C-2 or C-4 to give 2 regioisomers. Two unsaturated ketones with lambdamax = 230 nm and lambdamax = 241 nm are yielded during dehydrobromination. Use Woodward-Fieser rules to distinguish between the two.Reaction of C6H5CH2CH2OH with CH3COCl affords compound W, whichhas molecular formula C10H12O2. W shows prominent IR absorptions at3088–2897, 1740, and 1606 cm−1. W exhibits the following signals in its1H NMR spectrum: 2.02 (singlet), 2.91 (triplet), 4.25 (triplet), and 7.20–7.35(multiplet) ppm. What is the structure of W?Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reactionoccurs.a. H2 + Pd-Cb. H2 + Lindlar catalystc. Na, NH3d. CH3CO3He. [1] CH3CO3H; [2] H2O, HO–f. [1] OsO4 + NMO; [2] NaHSO3, H2Og. KMnO4, H2O, HO–h. [1] LiAlH4; [2] H2Oi. [1] O3; [2] CH3SCH3j. (CH3)3COOH, Ti[OCH(CH3)2]4, (–)-DETk. mCPBAl. Product in (k); then [1] LiAlH4; [2] H2O
- In the following cases rearrange the compounds as directed : (Delhi 2010)(i) In an increasing order of basic strength :C6H5NH2, C6H5 N(CH3)2, (C2H5)2NH and CH3NH2(ii) In a decreasing order of basic strength :Aniline, p-nitroaniline and p-toluidine(iii) In an increasing order of pKb values :C2H5NH2, C6H5 NHCH3, (C2H5)2NH and C6H5NH2Thank you for the answer, would it be possible to follow the path I have attached as well srarting from methanol ---> CH3Br -----> CH3MgBr-------> (H3C)CH-CH2OH ----> E1 IsobutaleneDevise a synthesis of (E)-1-phenylhex-1-ene (CH3CH2CH2CH2CH = CHPh) using hydrocarbons having ≤ 6 C’s and a Suzuki reaction as one of the steps.
- The crocodile, which can remain under water without breathing for up to 1 h, drowns its air-breathing prey and then dines at its leisure. An adaptation that aids the crocodile in doing so it that it can utilize virtually 100% of the O2in its blood whereas humans, for example, can extract only ~65% of the O2in their blood. Crocodile Hb does not bind BPG. However, crocodile deoxyHb preferentially binds HCO3ꟷ. How does this help crocodile obtain its dinner? Explain your answer.Stereoisomers of α-bromocinnamic acid: draw the reaction mechiansim with arows for the dehydrobromination of 2,3-dibromo-3-phenylpropanoic acid with ethanol and KOH to produce (Z)-α-bromocinnamic acid and (E)-α-bromocinnamic acid. Also draw the transition state for The (Z)-isomer syn-periplanar transition state and anti-periplanar transition state of the (E)-isomer.The reaction of 2-ethyl-1-pentene with Br2, with H2 + Pd/C, or with R2BH/THF followed by aqueous HO- + H2O2 leads to a racemic mixture. Explain why a racemic mixture is obtained in each case.
- Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by thecatalytic conversion of acetylene to benzene: 3C2 H2(g) ⇌ C6 H6(g). Which value of Kc would make this reactionmost useful commercially? Kc ≈ 0.01, Kc ≈ 1, or Kc ≈ 10. Explain your answerSharpless epoxidation of allylic alcohol X forms compound Y. Treatmentof Y with NaOH and C6H5SH in an alcohol–water mixture forms Z. Identifythe structure of Y and draw a mechanism for the conversion of Y to Z.Account for the stereochemistry of the stereogenic centers in Z. Z hasbeen used as an intermediate in the synthesis of chiral carbohydrates.