Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry
Section4.4: Conformations Of Cycloalkanes
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Answer number 6 "Calculate  ΔH and ΔS for each reaction. Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain."

I included the calculated results for ΔH and ΔS of each of the 5 reactions below the question. ΔH is in kcal/mol and ΔS is cal/(mol*K). 

6. Calculate AH and AS for each reaction. Do the magnitudes of these
thermodynamic parameters match what you expect for a cycloaddition
reaction? Explain.
Calculated results for AH and AS of each of the 5 reactions:
1. ethene + cis-1,3-butadiene
cyclohexene
AH: - 51.66 kcal/mol
As: - 43.466 cal/(mol*K)
2. cyclopentadiene + maleic anhydride → endo product
AH: -77.04 kcal/mol
As: - 52.292 cal/(mol*K)
3. cyclopentadiene and maleic anhydride -
→ exo product
Дн: - 114.6 kcal/mol
As: -51.76 cal/(mol*K)
4. furan + maleic anhydride
→ endo product
AH: 34.13 kcal/mol
As: -47.35 cal/(mol*K)
5. furan + maleic anhydride-
→ exo product
Дн: - 18.11 kcal/mol
As: - 49.27 cal/(mol*K)
Transcribed Image Text:6. Calculate AH and AS for each reaction. Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain. Calculated results for AH and AS of each of the 5 reactions: 1. ethene + cis-1,3-butadiene cyclohexene AH: - 51.66 kcal/mol As: - 43.466 cal/(mol*K) 2. cyclopentadiene + maleic anhydride → endo product AH: -77.04 kcal/mol As: - 52.292 cal/(mol*K) 3. cyclopentadiene and maleic anhydride - → exo product Дн: - 114.6 kcal/mol As: -51.76 cal/(mol*K) 4. furan + maleic anhydride → endo product AH: 34.13 kcal/mol As: -47.35 cal/(mol*K) 5. furan + maleic anhydride- → exo product Дн: - 18.11 kcal/mol As: - 49.27 cal/(mol*K)
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