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- The following figure shows the energy profile of a nucleophilic substitution reaction. Potential energy :ÖH H HII.C H C-1 H HO--C---I HH Reaction coordinate H -CH HO–CHITH H + 1 According to this, it is correct to affirm: O The activation energy (4G°) shows that it is thermodynamically favorable. O Represents a reaction that occurs in one step where a pentavalent chemical species is formed. O The intermediate has lower energy than any transition state. O The formation of the intermediate releases energy and is therefore thermodynamically favourable.The order from most reactive to least reactive with aqueous ammonia is (А) CH--o-č-CH, * CH,--oCH,CH, * CH,--a CH--č-OCH,CH, ° CH,--c³ CH---o-č-CH, > CH3-C-OCH2CH3 | CH3-C-CI | (В) %3D > CH3-C-CI CH3-C-0-C-CH3 (C) > CH3-C-CI CH3-C-OCH2CH3 CH3-C-0-C-CH3 (D) || > CH3-C-CI CH3-C-0-C-CH3 CH3-C-OCH2CH3Which of the following structures contribute(s) to the resonance hybrid of the intermediate formed when bromobenzene undergoes para-chlorination? Br+ Oll O III ONV OI :Br: H CI: All of the above H || :Br: H CI: E ||1 H IV
- 0 a +H=BC: Where are the curved arrow poshing mechanism as well as the non-bonding electrons. What are the initiation and progation Steps? •What are the two termination Steps for the reaction. B. с A. В. C. D. Brz HV - + • Br: → H-Br: + → + • Br: H-Br: + H + • Br: → H-BC: + •Where are the curved arrows pushing the reaction with bromine atom? What are the radical product including the resonance contributors • Rane the reaction in order of increasing rate. what is the explanation that includes the term Hammond Poštutate? H2 PJ/C HBI Br: 1.BH 3. THE 2. NaOHV/H₂O₂ Bcz (2) hu x 1. What are the major organic productes) of the reaction. Include all Stereochemistry and identify any meso compounds. E.. все hu 2. Would the solution of the products be optically active of not active. what would be the Ceason for the choice?Identify the transition state for the reaction between tert-butyl chloride and sodium hydroxide. H H-c-H 8- 8- HO---- C- CI H3C CH3 H 8- Но- -H----c-H 8- HạC-C- ČH3 -CI H-c-H 8+ 8+ HO---- CI H3C CH3 H. &+ HO-----H----C 8+ H3C-C----CI ČH3 %3Complete the following reactions schemes by drawing the messing intermediate/products: SeO2 i) Ethanol H* ii) H20 OH HỎ OH 1) 4 equivqalents of H2/ Pd iii) 2) KMNO,/H* O3 iv) Zn Ag,O/ H2O excess Mel K,CO3 Нeat v) CH3
- HO HO Ме— „Me `NH2 H2 F G (d) What type of mechanism is involved in this reaction? Explain the abbreviation used. (e) Would Me-F react with F in the same way? Explain. (f) Why does the N react with Me-l in preference to the O or any of the C atoms?How many acid-base steps occur in this mechanism? :OH fö OH ₂ H CI: -H₂O (C5H12O) (CsH3O*) :CI: :CI:- yox (C5H1*) (C5H₁1CI)Consider the following overall reaction, which will be discussed in Chapter 20. H,C-CEN NH3 HOO H,C Below is a proposed mechanism for this reaction. Use the rules we learned in this chapter to evaluate whether each step in the proposed mechanism is reasonable. For each step that is not reasonable, explain why. :ÖH () H,C-CEN: H3C OH OH (i) + H,C H3C OH OH (ii) H,C H,C OH (iv) + H,O: H,C H,C OH (v) H3C H3C OH H. (vi) :NH, NH. H,C H,C
- Which is the correctly drawn transition state for this SN2 reaction? O O wil. Br H !!! Br 8- H NC Br 8- d CN III. -CN 8- 8- + Br-CN H d d Br CN H + + #Q2- Which one of the following reaction is unreasonabl? A) NaOH(aq)+HCl(aq)-NaCla+H₂O B) H2(g)+1/202)→ H₂Op AHneutralization=-851.5kJ/mol =-283.5kJ/mol AHormation C) CH3COOH + H₂O-CH:COO(g) + H AHassociation = +213.5kJ/mol D) Mg(+2HCl → MgCha) + H₂ - AHformation =+315.5kJ/mol Q3- If A 25.0 mL of diluted bleach solution has required 30 mL of 0.30 M Na S,O; to reach the endpoint of the titration. Calculate the mass percent of NaCIO in the original sample (Molar mass NaCIO = 74.5 g/mol). Assume the density of bleach solution is 1.084g/mL and the dilution factor is 10. B) 9.96% C) 0.996% D) 12.4% A) 19.92% and the coloH но. но HO Ethylene oxide is the starting material for the synthesis of 1,4-dioxepane. Draw curved arrows to show the movement ofelectrons in this step of the reaction mechanism. Arrow-pushing Instractions HO+ но H,ö: HO: :o: :o: I-
