Draw the major and minor product that could be formed when 1-methoxy-1,3- butadiene reacts with 2- methylpropenoic acid. Ignore any stereochemistry.
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- When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.(a) Propose structures for products A and B. (Hint: In many cases, an allylic carbocationis more stable than a bromonium ion.)(b) Propose a mechanism to account for formation of both A and B.(c) Show why A predominates at -15 °C and B predominates at 60 °C.(d) If you had a solution of pure A, and its temperature were raised to 60 °C, what wouldyou expect to happen? Propose a mechanism to support your predictionM 6 write the principal product in a, c & e and the neccesary reactives for b, d & f in the following reactions :
- The HCo(CO)4complex can catalyze the isomerization of pure cis-2-butene to a mixture of cis-2-butene, trans-2-butene, and 1-butene. Propose a mechanism. Carefully show the process using wedges and dashes to indicate stereochemistry of each intermediate.Order the following organic compounds by increasing E1 reactivity with the highest reactivity starting first. A. 2-bromopropane B. 2-chloropropane C. 1-bromobutane D. 2-bromo-2-methylpropane E. bromomethanePredict the organic product(s) of the reaction of 2-butene with each reagent. Q.) Hg(OAc)2, H2O
- 4 Part 3. Give the IUPAC names of the following compoundsPart 5: Predict the products, if any, of the following reactions.Treatment of but-1-ene with hot KMno4/OH- gives product D, and subsequent acidification of the mixture gives product E. What are D and E. Give reaction equations.When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.(a) Propose structures for products A and B. (Hint: In many cases, an allylic carbocationis more stable than a bromonium ion.)
- LDA/THF, 78°Clongrightarrow Predict the major product of the following a- halogenation/a - alkylation reactions under the given reaction conditions.is steric hinderance not an issue here? why when reacting with KOC(CH3)3 does it yield 2-isopropyl-1-pentene and it yields 2,3-dimethyl-2hexene here?When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.) Propose a mechanism to account for formation of both A and B