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- Draw the organic product(s) of the following reaction. You do not have to consider stereochemistry. Include cationic counter-ions, e.g., Na+ in your answer, but draw them in their own sketcher. If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-down menu.(10pts) Compound A, C10H16, was found to be optically active. On catalytic reduction over a palladium catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, CioH2o. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid (CHCOOH). The other fragment, compound C, was an optically active carboxylic acid, C8H14O2. Write reactions, and draw the correct structures for A-C, explain your answer in detail.A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired configuration. a. Label this stereogenic center as R or S. b. A well-known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship. d. Suggest a reagent to convert A to the single stereoisomer X.
- A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired conguration.a. Label this stereogenic center as R or S.b. A well known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.c. Suggest a reagent to convert A to the single stereoisomer X.You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. Draw phosphate groups, when present, as in the question: in basic form and with a phosphorous oxygen double bond.Monensin (1) is a potent antibiotic. JACS 1980, 102, 2118-2120. 1. Use arrows provided a pathway from (1) to (2) when we add a mild base sodium bicarbonate followed by iodine (I2). 2. What was a similar reaction between Br2 and an alkene? What did we name the intermediate?
- Complete the mechanism for the following reaction by filling in the boxes. Do not show stereochemistry in the structures. Be sure to include lone pairs on heteroatoms and any charges where necessary.Draw the product of an SN2 reaction shown below. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts.Draw the product of an SN2 reaction shown below. Use wedge and dash bonds to indicate stereochemistry where appropriate. Indicate inorganic byproducts.
- Question #16a. Please provide the missing reactants, reagents, or products for the following reaction sequences below. If a sequence leads to a race mic mixture you should indicate +enantiomer.A student was randomly given compounds E and F from the group of compounds below and asked to identify them according to their functional group. The student initially thought this to be easy, only to discover that he was embarking on some kind of Herculean task. If you were to correctly advise the student, which test will be most appropriate to distinguish compounds E and F? A. Brady's test (2,4-DNP) B. Reaction with Jones's reagent C. Tollen's test D. Iodoform testEnolates are formed by deprotonation of an α-carbon hydrogen. Answer the following questions about enolate formation. In the molecule shown, select the α-carbon hydrogen that would be removed to form an enolate when sodium hydroxide is used as a base. (use photo to answer this question). Then, Draw the thermodynamic enolate that results for the molecule in Part 1. Draw only the enolate resonance form that includes a formal charge on the α carbon. Be sure to indicate that formal charge as well as any lone pair of electrons in your answer.
