Draw the organic products formed in each of the following reactions. (i). (ii) (iii) (iv) (v) +:C=C-H + H₂O CH₂C=CCH₂CH3 HgSO4, H₂SO4 Na, NH3 2 equiv Br₂ (1) Sia₂BH.THF (2) H₂O₂ NaOH
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- Devise a synthesis of each of the following compounds. Besidesinorganic reagents, you may use hydrocarbons and halides having ≤ 6C′s, and CH2=CHCOOCH3 as starting materials. Each synthesis must use at least one of the carbon–carbon bond-forming reactions.Several sulfonylureas, a class of compounds containing RSO2NHCONHR, are useful drugs as orally active replacements for injected insulin in patients with adult-onset diabetes. These drugs decrease blood glucose concentrations by stimulating b cells of the pancreas to release insulin and by increasing the sensitivity of insulin receptors in peripheral tissues to insulin stimulation. Tolbutamide is synthesized by the reaction of the sodium salt of p-toluenesulfonamide and ethyl N-butylcarbamate . Propose a mechanism for this step.Compound X is optically inactive and has the formula C 16H 16Br 2. On treatment with strong base, X gives hydrocarbon Y, C 16H 14. Compound Y absorbs 2 equivalents of hydrogen when reduced over a palladium catalyst and reacts with ozone to give two fragments. One fragment Z, is an aldehyde with formula C 7H 6O. The other fragment is glyoxal, (CHO)2. Which of the following answers is correct? Select all that are correct.
- Give the expected organic product when phenylacetic acid, PhCH2COOH, is treated with reagent Q.)CH3MgBr (one equivalent)Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by thecatalytic conversion of acetylene to benzene: 3C2 H2(g) ⇌ C6 H6(g). Which value of Kc would make this reactionmost useful commercially? Kc ≈ 0.01, Kc ≈ 1, or Kc ≈ 10. Explain your answerRank the species below in order of increasing nucleophilicity in protic solvent. I. H2O II. CH3S— III. CH3COO— IV. t-BuO— I, II, IV, III I, III, II, IV I, III, IV, II I, II, III, IV
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