Draw the structure(s) of the major organic product(s) of the following reaction.+1. in benzene2. aqueous HCI•You do not have to consider stereochemistry.•You do not have to explicitly draw H atoms.•Do not include lone pairs in your answer. They will not be considered in the grading.Do not include the amine from which the enamine was derived.•• If no reaction occurs, draw the organic starting material.•Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.•Separate multiple products using the + sign from the drop-down menu.?nChemDoodleⓇ< >

The product can undergor further hydrolysis to give the acid.

Answered: Draw the structure(s) of the major…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter20: Acidity And Pka Of Phenols

Section: Chapter Questions

Problem 11E

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Assume that 2-chloropropane reacts with CN− in an SN2 reaction. Use the JSME editor () to draw the structure of the substitution product of the reaction. The guide on how to draw your structure can be found here Important Note: When drawing the structures in the JME editor please adhere to the following formats: 1. If the nucleophile is OH−, DO NOT manually add the "H" to the final product 2. If the nucleophile is CN−, be sure to include the appropriate bonding between the C and N in the final product
1) Based on the Material Safety Data Sheets (MSDS) for the compounds, which of the compounds in this experiment is the most hazardous, and why (you have been given a representative aryl halide rather than all of the alkenes – as the products are all new, there’s not a simple answer to gauge their potential hazard)? 2,3-dihydrofuran,2-Mercaptobenzimidazole,Selectfluor, Dimethylformamide,dichloromethane-methylene chloride.
Several reagents and several organic structures are shown below. Construct a multistep synthetic route from the reactant 2-methyl-1-butene to the product 3-bromo-2-methyl-2-butanol by dragging the appropriate pieces into the bins. Note that each bin will hold only one item, and not every given reagent or structure will be used.
In the chemical reaction between 1-Bromobutane and ethanolic silver nitrate solution, a precipitate is barely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially the SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.
Draw structure of a tertiary alcohol, give its correct name and the show the REACTION MECHANISM for the formation of an alkyl halide from this alcohol. (7) HINT: - The reaction is SN1, it takes place through 3 STEPS and TWO carbocations forms as intermediates. - The reaction was carried in the presence of an acid and in the presence of halide ions, and not at elevated temperature. - Halide ions are good nucleophiles (they are much stronger nucleophiles than water), and since halide ions are present in high concentration, most of the carbocations react with an electron pair of a halide ion to form a more stable species, the alkyl halide product. - OH group is a poor leaving group, thus the alcohol gets protonated first.
Phineas and Ferbs, two brothers who enjoy vacations, doing fun things every summer. This summer the brothers and their friends carry out an organic synthesis with an unknown compound (L1) that contains 52% Carbon, 6% Hydrogen and 42% bromine, this compound (L1) is treated with magnesium in ether to obtain L2 , which reacts violently with D2O for 1-methyl cyclohexene with a deuterium atom in the methyl group (L3). The L2 reaction is treated with acetone followed by hydrolysis to give L4. Heating L4 with concentrated sulfuric acid gives L5, which decolors the bromine, obtaining L6. L5 undergoes hydrogenation with excess hydrogen and platinum as a catalyst giving rise to isobutyl cyclohexane. Determine the structures of compounds L1 through L6.
Rearrangements can occur during the dehydration of 1° alcohols even though no 1° carbocation is formed—that is, a 1,2-shift occurs as the C— OH2+ bond is broken, forming a more stable 2° or 3° carbocation, as shown in Equation [1]. Using this information, draw a stepwise mechanism for the reaction shown in Equation [2]. We will see another example of this type of rearrangement in Section 16.5C.
Explain the following result. Although alkenes are generally more reactive than alkynes toward electrophiles, the reaction of Cl2 with but-2-yne can be stopped after one equivalent of Cl2 has been added.
The addition of an alcohol to an acid chloride is an example of alcoholysis (alcohol addition with bond breakage). Consider the alcoholysis reaction below and answer the questions that follow. 1. Show the tetrahedral intermediate that is formed after the nucleophilic addition of the alcohol to the acid chloride. Be sure to include all lone pair electrons and formal charges on your intermediate structure. 2. Show the final product of this alcoholysis reaction that forms after the intermediate you made in Part 1. Do not include inorganic or charged products in your answer. Be sure to include all lone pair electrons and formal charges.
Draw the products and necessary reagents of the three step retrosynthetic reaction sequence shown below. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts. Please choose from the following options for each of the reagents. (top reagents options) A. HNO3, cat. H2SO4 B. SO3, cat. H2SO4 C. CH3C(=O)Cl, AlCl3 D. Cl2, FeCl3 E. H2O, HCl (reagents option to the right) (top reagents options) A. HNO3, cat. H2SO4 B. SO3, cat. H2SO4 C. CH3C(=O)Cl, AlCl3 D. Cl2, FeCl3 E. H2O, HCl
1. What type of reaction is occuring in step 3? (halogenation, hydrohalogenation, reduction, keto–enol tautomerism, dehydrohalogenation, acid-catalyzed hydration, base-catalyzed hydration) 2. Which reagent is necessary for step 3? (Br2, HBr, H2/Pt, NaNH2, H20/H2SO4/HgSO4)
In the following reaction Series, write down the appropriate reagents that can be used where there are question marks

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