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- Consider 1-bromopropane, CH3CH2CH2Br. (a) Draw a Newman projection for the conformation in which CH3 and -Br are anti (dihedral angle 180°). (b) Draw Newman projections for the conformations in which - CH3 and -Br are gauche (dihedral angles 60° and 300°). (c) Which of these is the lowest energy conformation? (d) Which of these conformations, if any, are related by reflection?How many stereoisomers are there of 2, 3 dibrmopentane? Call all of them and label them R, S. Are any of them Meso?Draw every stereoisomer for 1‑bromo‑2‑chloro‑1,2‑difluorocyclopentane. Use wedge‑and‑dash bonds for the substituent groups, and be sure that they are drawn on the outside of the ring, adjacent to each other. Clearly show stereochemistry by drawing the wedge‑and‑dashed bonds like the example. You should replace the X with the appropriate halide.
- Complete the Newman projection below to draw the most stable conformation of 3-methylpentane, looking down the C2-C3 bond. Identify each substituent using "H" for hydrogen and "Me" for methyl. a= b= c= d=Stereoisomers share the same connectivity and differ only in the way their atoms are arranged in space. Draw the structure of a compound that is a stereoisomer of cis-1,2-dimethylcyclobutane.(Note that the question asks for a different stereoisomer of the named compound and not the named compound itself.)Use the wedge/hash bond tools to indicate stereochemistry where it exists.In cases where there is more than one answer, just draw one.The following are drawing of various co-workers of several different stereoisomers.5a. Pick one drawing, circle it and all confirmed drawings of that same stereoisomers.B. Pick a drawing that is not already circled and repeat for the new stereo isomers but box in with squares. C. Repeat for the third stereo isomer but with triangles.Also solve 5b and 5c .
- Rank the following groups in order of decreasing priority. −H, −CH3, −Cl, −CH2ClUsing the wedge-and-dash notation, draw the nine stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane. A. From the nine stereoisomers, identify one pair of enantiomers. B. Draw the most stable conformer of the most stable stereoisomer.For 1,2-dichloroethane: a.Draw Newman projections for all eclipsed conformations formed by rotation from 0° to 360° about the carbon-carbon single bond. b.Which eclipsed conformation(s) has (have) the lowest energy? Which has (have) the highest energy? c.Which, if any, of these eclipsed conformations are related by reflection?
- 1. Estimate the relative stabilities of the 4 conformationseclipsed and eclipsed n-pentane by drawing the corresponding Newman projections in descending order according to their stability. Place the most stable or lowest energy on the left. 2. Explain what the difference in energy between the most stable and the least stable is due to. 3. What is the difference in stability between the two staggered conformations?Draw the bond-line formula of 3,4-dimethylhexane. Is geometric isomerism observed in 3,4-dimethylhexane? What structural features must be present for stereoisomers to exist? (4 marks) (b) (1) Using Fischer projection, draw all the stereoisomers of 3-chloro-2-hydroxypentanoic acid. (4 marks) (ii) Assign the chiral centre(s) with R/S configurations in part (b)(i). Indicate which are enantiomers, diastereomers and meso compounds (if any).3. Which stereoisomer can obtain the least amount of conformational strain, cis- or trans-1,3-dimethylcyclohexane? What is the difference in strain energy between these two m