e diastereomers?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter5: Stereochemistry At Tetrahedral Centers
Section5.SE: Something Extra
Problem 74AP: cis-1,2-Dimethylcyclohexane is optically inactive even though it has two chirality centers. Explain.
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Consider the following Fischer
Projection Formulas:
сно
сно
-OH
CHO
CHO
H-
OH
H-
но-
но-
HO-H
ČH2OH
но-
CH2OH
но
сно
IV
H-
OH
ČH2OH
II
III
Which are diastereomers?
III & IV
I & II
O I & I
Il & IV
Transcribed Image Text:Consider the following Fischer Projection Formulas: сно сно -OH CHO CHO H- OH H- но- но- HO-H ČH2OH но- CH2OH но сно IV H- OH ČH2OH II III Which are diastereomers? III & IV I & II O I & I Il & IV
Based on the given planar structure
of 1,2,3-trichloro-4-
methylcyclohexane, which of the
following structures corresponds to
the most stable chair conformation
of the compound (Figure below)?
CI
ÇI
H3CD
ÇI
H3C
CI
CI
ÇI
-CI
CH;CI
CI
CI
ČHCI
Transcribed Image Text:Based on the given planar structure of 1,2,3-trichloro-4- methylcyclohexane, which of the following structures corresponds to the most stable chair conformation of the compound (Figure below)? CI ÇI H3CD ÇI H3C CI CI ÇI -CI CH;CI CI CI ČHCI
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