(e) (p) ()) "HIVIT MgBr (q) (e) 9SH nucleophiles in a-e. Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the
(e) (p) ()) "HIVIT MgBr (q) (e) 9SH nucleophiles in a-e. Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 18CTQ
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Question
Transcribed Image Text:CH3
Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the
nucleophiles in a-e.
(a)
LIAIHA
(e)
MgBr
(e)
(p)
())
Expert Solution
Step 1 Nucleophile attack in Organic reaction
a) CH3SNa Methanethiol , generate a soft nucleophile ,center at sulfur atom.
Soft nucleophile will attack on Soft electrophillic center i.e. on Alkene Carbon
b) This is an Example of Witting Reaction, Alkene will Form by replacing carbonyl center
c) This is an example of Cross Aldol Reaction. Nucleophile will attack on carbonyl center
d) Grignard reagent, a hard nucleophile , attack on carbonyl center of reactant
e) LiALH4 a reducing agent, used for reduction of carbonyls.
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