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A: Known: ∆HfoCOg=-110.5 kJ/mol.∆HfoH2O(g)=-241.8 kJ/mol∆HfoCO2(g)=-393.5 kJ/mol∆HfoH2(g)=0 kJ/mol
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A:
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A: Option A is correct answer. True.
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Q: What
A:
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Q: hich element es each
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A: True
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A:
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- What arethe differencesbetween an open, a closed, and an isolated system?Describe an example of each.A linear molecule may rotate about two axes. If the molecule consists of N atoms, then there are 3N- 5 vibrational modes. Use the equipartition theorem to estimate the total contribution to the molar internal energy from translation, vibration, and rotation for (a) carbon dioxide, CO2, and (b) dibromoethyne, C2Br2, at 2000 K. In contrast, a nonlinear molecule may rotate about three axes and has 3N- 6 vibrational modes. Estimate the total contribution to the molar in ternal energy from translation, vibration, and rotation for (c) nitrogen dioxide, NO2, and (d) tetrabromoethene, C2Br4,at 2000 K. In each case, first assume that all vibrations are active; then assume that none is.A certain molecule can exist in either a nondegenerate singlet state or a triplet state (with degeneracy of 3). The energy of the triplet exceeds that of the singlet by ε. When ?=??(where T is a set value, i.e., ? is a constant), calculate the values of the molecular partition function, molar heat capacity, and molar entropy. Assume the molecules are distinguishable and independent
- Calculate the value of Cp at 298K and 1 atm pressure predicted for CH4(g) and C2H4(g) by the classical equipartition theorem. Compare the predicted results with the experimental results (see OGB Appendix D) and calculate the percent of the measured value that arises from vibrational degrees of freedom.An NO molecule has a doubly degenerate electronic ground state and a doubly degenerate excited state at 121.1 cm−1. Calculate and plot the electronic contribution to the molar heat capacity of the molecule up to 500 K.Consider a system consisting of two oppositely chargedspheres hanging by strings and separated by a distance r1,as shown in the accompanying illustration. Suppose theyare separated to a larger distance r2, by moving them apart.(a) What change, if any, has occurred in the potential energyof the system? (b) What effect, if any, does this process haveon the value of ΔE? (c) What can you say about q and w forthis process?
- JustifyTrouton"s rule. What are the sources of discrepancies?Use the equipartition principle to estimate the value of γ = Cp/CV for carbon dioxide. Do this calculation with and without the vibrational contribution to the energy. Which is closer to the experimental value at 25 °C?2. Calculate the total molar entropy of HF at 298K. The vibrational frequency is 3960 cm-1 and the rotational constant is 20.6 cm-1.
- Discuss the relation between the thermodynamic and statistical definitions of entropy.A standard sample of Argon gas is 22.4L, 1.00atm, 1.00mol, 273.15K. In the right setups excited gas can be tricked into using heat and giving away photons of light. If the sample gave off 0.01mol of 3,634nm light by converting thermal energy into those photons find the new final temp of the gas. SAr = 0.52J/gK