e) Use (; a²p Find the value of Vm at which both of these deriva- T to find aVm tives are zero.

Advanced Engineering Mathematics
10th Edition
ISBN:9780470458365
Author:Erwin Kreyszig
Publisher:Erwin Kreyszig
Chapter2: Second-order Linear Odes
Section: Chapter Questions
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just question e. do it step by step

1. Consider the van der Waals equation
(1)
а
(Vm – b) – RT = 0
m
where p, Vm, T, are, respectively, pressure, molar volume, and temperature and R,
a, and b are constants.
a) Find
ƏVm
ƏT
:) by computing the differential of (1) at constant p.
b) Find
2) by computing the differential of (1) at constant T.
aVm
T
c) Use the expressions for ().
:) and suitable relationships between
aVm
and
ƏT
T
partial derivatives to find
ƏT
Vm
and () and suitable relationships between
aVm
ƏT
d) Use the expressions for
aT
Vm
(*).
partial derivatives to find
aVm
T
(盘)。
to find (
Find the value of Vm at which both of these deriva-
e) Use
av2
T
tives are zero.
Transcribed Image Text:1. Consider the van der Waals equation (1) а (Vm – b) – RT = 0 m where p, Vm, T, are, respectively, pressure, molar volume, and temperature and R, a, and b are constants. a) Find ƏVm ƏT :) by computing the differential of (1) at constant p. b) Find 2) by computing the differential of (1) at constant T. aVm T c) Use the expressions for (). :) and suitable relationships between aVm and ƏT T partial derivatives to find ƏT Vm and () and suitable relationships between aVm ƏT d) Use the expressions for aT Vm (*). partial derivatives to find aVm T (盘)。 to find ( Find the value of Vm at which both of these deriva- e) Use av2 T tives are zero.
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