e. Do electrons flow from the Mg electrode to the Ni electrode or vice-versa? f. If a salt bridge containing NaNO3 connects the two half cells, in which direction do the nitrate ions move? g. Calculate AG for this cell at 25 °C when [Ni²+] = 0.10 M and [Mg2+] = 0.90 M. h. Calculate AG for this cell at 25 °C when [Ni²+] = 1.0 M and [Mg2+] = 1.0 M. i. Compare the magnitude of your AG answers in parts g and h, above. Is this reaction becoming more spontaneous or less spontaneous? Explain this observation using Le Chatelier's Principle.

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Chapter17: Electrochemistry
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Question: Please help guide me through this! Also, E° (Volts) for Mg²+ (aq) + 2 e -> Mg (s) is -2.37 V. Ni²+ (aq) + 2 e -> Ni (s) is -0.25 V. Only parts (E,f,g,h,i) please complete
3. You decide to assemble an electrochemical cell based on the half reactions Mg2+ / Mg(s) and Ni²+ / Ni(s).
a. Write the equation for the product favored reaction that occurs in the cell.
b. Calculate E' for this product-favored reaction at 25 °C.
What is the better reducing agent, Mg or Ni?
d. Calculate Ecell for this reaction at 25 °C, [Ni²+] = 0.10 M and [Mg2+] = 0.90 M. (the Nernst equation, E=E - (RT/nF) In Q
C.
e. Do electrons flow from the Mg electrode to the Ni electrode or vice-versa?
f. If a salt bridge containing NaNO3 connects the two half cells, in which direction do the nitrate ions move?
g. Calculate AG for this cell at 25 °C when [Ni²+] = 0.10 M and [Mg2+] = 0.90 M.
h. Calculate AG for this cell at 25 °C when [Ni2+] = 1.0 M and [Mg2+] = 1.0 M.
i. Compare the magnitude of your AG answers in parts g and h, above. Is this reaction becoming more spontaneous or less
spontaneous? Explain this observation using Le Chatelier's Principle.
Transcribed Image Text:3. You decide to assemble an electrochemical cell based on the half reactions Mg2+ / Mg(s) and Ni²+ / Ni(s). a. Write the equation for the product favored reaction that occurs in the cell. b. Calculate E' for this product-favored reaction at 25 °C. What is the better reducing agent, Mg or Ni? d. Calculate Ecell for this reaction at 25 °C, [Ni²+] = 0.10 M and [Mg2+] = 0.90 M. (the Nernst equation, E=E - (RT/nF) In Q C. e. Do electrons flow from the Mg electrode to the Ni electrode or vice-versa? f. If a salt bridge containing NaNO3 connects the two half cells, in which direction do the nitrate ions move? g. Calculate AG for this cell at 25 °C when [Ni²+] = 0.10 M and [Mg2+] = 0.90 M. h. Calculate AG for this cell at 25 °C when [Ni2+] = 1.0 M and [Mg2+] = 1.0 M. i. Compare the magnitude of your AG answers in parts g and h, above. Is this reaction becoming more spontaneous or less spontaneous? Explain this observation using Le Chatelier's Principle.
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