E°cell =    1.9791 ΔG° =    -381.91 What is K?

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter9: Energy And Chemistry
Section: Chapter Questions
Problem 9.23PAE: 9.23 Which system does not work: (a) E=436J , q=400J ; or E=317J , q=347J ?
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cell =    1.9791

ΔG° =    -381.91

What is K?

Expert Solution
Step 1

The relationship between the E0cell and equilibrium constant is given by 

RTln(K) = nFE0cell 

where R = gas constant = 8.314 J/K.mol

T = Temperature in Kelvin = 298 K                                               ( assuming it to be room temperature as not given)

K = equilibrium constant 

n = number of electrons transferred in the reaction = 2       ( the overall reaction will be found by cancelling 2 electrons while adding the half reactions) 

F = Faraday's constant = 96500 C 

 

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