ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow

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Author:William L. Masterton, Cecile N. Hurley
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Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 35QAP: Azomethane decomposes into nitrogen and ethane at high temperatures according to the following...
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13.55

ethane
2C,H6(g) +702(g) 4C0,(g) + 6H,O(1)
Explain why it is unlikely that this equation also rep-
resents the elementary step for the reaction.
13.54 Specify which of the following species cannot be
isolated in a reaction: activated complex, product,
Me
intermediate.
Me
Problems
13.55 The rate law for the reaction
13.6 Cata
2NO(g) + Cl,(g) 2NOCI(g)
Review Qu
is given by rate = k[NO][Cl,]. (a) What is the
order of the reaction? (b) A mechanism involving
the following steps has been proposed for the
reaction:
13.59 Ho
%3D
13.60 Wh
13.61 A c
ro
tion
NO(g) + Cl2(g) NOCI (g)
NOCI,(g) + NO(g) 2NOCI(g)
->
tem
13.62 Dist
hete
If this mechanism is correct, what does it imply
about the relative rates of these two steps?
indu
13.56 For the reaction X, + Y+Z
XY+ XZ it is
talys
found that doubling the concentration of X, doubles
the reaction rate, tripling the concentration of Y tri-
ples the rate, and doubling the concentration of Z
has no effect. (a) What is the rate law for this reac-
tion? (b) Why is it that the change in the concentra-
tion of Z has no effect on the rate? (c) Suggest a
mechanism for the reaction that is consistent with
13.63 Are
gene
13.64 The
quite
this f
Problems
the rate law.
13.65 The
mech
and th
13.57 The rate law for the decomposition of ozone to mo-
lecular oxygen
diate
20,(g)
-30,(g)
and B
is
tow
Transcribed Image Text:ethane 2C,H6(g) +702(g) 4C0,(g) + 6H,O(1) Explain why it is unlikely that this equation also rep- resents the elementary step for the reaction. 13.54 Specify which of the following species cannot be isolated in a reaction: activated complex, product, Me intermediate. Me Problems 13.55 The rate law for the reaction 13.6 Cata 2NO(g) + Cl,(g) 2NOCI(g) Review Qu is given by rate = k[NO][Cl,]. (a) What is the order of the reaction? (b) A mechanism involving the following steps has been proposed for the reaction: 13.59 Ho %3D 13.60 Wh 13.61 A c ro tion NO(g) + Cl2(g) NOCI (g) NOCI,(g) + NO(g) 2NOCI(g) -> tem 13.62 Dist hete If this mechanism is correct, what does it imply about the relative rates of these two steps? indu 13.56 For the reaction X, + Y+Z XY+ XZ it is talys found that doubling the concentration of X, doubles the reaction rate, tripling the concentration of Y tri- ples the rate, and doubling the concentration of Z has no effect. (a) What is the rate law for this reac- tion? (b) Why is it that the change in the concentra- tion of Z has no effect on the rate? (c) Suggest a mechanism for the reaction that is consistent with 13.63 Are gene 13.64 The quite this f Problems the rate law. 13.65 The mech and th 13.57 The rate law for the decomposition of ozone to mo- lecular oxygen diate 20,(g) -30,(g) and B is tow
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