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- How does galvanic corrosion differ from uniform corrosion of iron?Consider the reaction A(g)+2B(g)C(g)+D(g) in a 1.0-L rigid flask. Answer the following questions for each situation (ad): i. Estimate a range (as, small as possible) for the requested substance. For example, [A] could be between 95 M and 100 M. ii. Explain how you decided on the limits for the estimated range. iii. Indicate what other information would enable you to narrow your estimated range. iv. Compare the estimated concentrations for a through d. and explain any differences. a. If at equilibrium [A]= 1 M. and then 1 mole of C is added, estimate the value for [A] once equilibrium is reestablished. b. If at equilibrium [B] = 1 M, and then 1 mole of C is added, estimate the value for [B] once equilibrium is reestablished. c. If at equilibrium [C] = 1 M, and then 1 mole of C is added, estimate the value for [C] once equilibrium is reestablished. d. If at equilibrium [D] = 1 M, and then 1 mole of C is added, estimate the value for [D] once equilibrium is reestablished.Suggest two ways in which the equilibrium concentration of Ag+ can be reduced in a solution of Na+, Cl-, Ag+, and NO3-, in contact with solid AgCl. Na+(aq)+CI(aq)+Ag+(aq)+NO3(aq)AgCI(s)+Na+(aq)+NO3(aq)H=65.9kJ
- . Suppose that for the reaction 2N2O(g)+O2(g)4NO((g))it is determined, at a particular temperature, that the equilibrium concentrations arc [NO(g)]=0.00341M,[N2O(g)]=0.0293M, and [O2(g)]=0.0325M. Calculate the value of K for the reaction at this temperature.In Table 12.1 (←Sec. 12-3a) the equilibrium constant for the reaction ⇋ is given as 4.2 × 1052. If this reaction is so product-favored, why can large piles of yellow sulfur exist in our environment (as they do in Louisiana and Texas)?Nitrogen, hydrogen, and ammonia are in equilibrium in a 1000-L reactor at 550 K. The concentration of N2 is 0.00485 M, H2 is 0.022 M, and NH3 is 0.0016 M. The volume of the container is halved, to 500 L. (a) Calculate the equilibrium constant. (b) Define y as the change in the concentration of nitrogen in the 500-L container. Is y positive or negative? (c) Write the iCe table and express the equilibrium constant in a polynomial in terms of y.
- The thermite reaction is 2Al(s) + Fe2O3(s) Al2O3(s) + 2Fe(s) (a) Calculate G for this reaction. (b) Calculate Keq for this reaction. Assume T = 298 K. You may have to do some mathematical manipulations to get your final numerical answer.When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so. This is followed by vigorous bubbling and the eventual disappearance of the foil. Explain these observations.What characterizes an electrolytic cell? What is an ampere? When the current applied to an electrolytic cell is multiplied by the time in seconds, what quantity is determined? How is this quantity converted to moles of electrons required? How are moles of electrons required converted to moles of metal plated out? What does plating mean? How do you predict the cathode and the anode half-reactions in an electrolytic cell? Why is the electrolysis of molten salts much easier to predict in terms of what occurs at the anode and cathode than the electrolysis of aqueous dissolved salts? What is overvoltage?
- Determine if the following reaction occurs spontaneously in the forward reaction: Ni (s) + Zn2+ (aq) ---> Ni2+ (aq) + Zn (s)the following reaction has an equiliberium constant Kc equal to 3.59 at 900°C (see image) (the cut off part says "if it is not")For the forward reaction, can I use H3O+ instead?