Except for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give (a) Given the relative sizes of F and CI, would you expect the first two F substitutions to be at axial or equatorial positions? O axial O equatorial This answer has not been graded yet. (b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.) O PCIF. O PCI3F2 O PCI,F3 O PFs O PCIĄF

Chemistry: Principles and Reactions
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Chapter7: Covalent Bonding
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Problem 76QAP: In each of the following molecules, a central atom is surrounded by a total of three atoms or...
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Except for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI3F2, ..
PF5.
(a) Given the relative sizes of F and CI, would you expect the first two F substitutions to be at axial or equatorial positions?
O axial
equatorial
This answer has not been graded yet.
(b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.)
PCIF4
PCI3F2
PCI2F3
PF5
PCI4F
Transcribed Image Text:Except for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI3F2, .. PF5. (a) Given the relative sizes of F and CI, would you expect the first two F substitutions to be at axial or equatorial positions? O axial equatorial This answer has not been graded yet. (b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.) PCIF4 PCI3F2 PCI2F3 PF5 PCI4F
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