Experiment Initial [HgCl,] Initial [C,O,²] Initial Rate of Formation of Cl- (M/min) 0.52x10 2.08 x 104 0.0836 M 0.202M (1) (2) (3) |(4) 0.0836 M 0.404M 1.06 x 10 1.27 x 104 0.0418 M 0.404M 0.0316 M a. What is the order for [HgCl,]? Justify your answer. b. What is the order for [C,O,]? Justify your answer. c. Write the rate law for this reaction.

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.33PAE: The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution....
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Experiment
Initial [HgCl,]
Initial [C,O,²]
Initial Rate of Formation of Cl-
(1)
(2)
(3)
(4)
(M/min)
0.52x10
2.08 x 10
1.06 x 10-4
0.0836 M
0.0836 M
0.202M
0.404M
0.0418 M
0.404M
0.0316 M
1.27 x 104
a. What is the order for [H9CI,]? Justify your answer.
b. What is the order for [C,0,]? Justify your answer.
c. Write the rate law for this reaction.
Transcribed Image Text:Experiment Initial [HgCl,] Initial [C,O,²] Initial Rate of Formation of Cl- (1) (2) (3) (4) (M/min) 0.52x10 2.08 x 10 1.06 x 10-4 0.0836 M 0.0836 M 0.202M 0.404M 0.0418 M 0.404M 0.0316 M 1.27 x 104 a. What is the order for [H9CI,]? Justify your answer. b. What is the order for [C,0,]? Justify your answer. c. Write the rate law for this reaction.
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