Find the enthalpy of neutralization of 75.5mL 1.00M aqueous sodium hydroxide with 40.7mL 1.00M hydrochloric acid if after mixing the two solutions the temperature went up 6.2∘C. Report the amount of the limiting reagent in mmol:   (enthalpies given: NaOH = -425.61, Cl- = -167.16, H+ = 0)

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter6: Thermochemistry
Section: Chapter Questions
Problem 68E: In a coffee-cup calorimeter, 1.60 g NH4NO3 is mixed with 75.0 g water at an initial temperature of...
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Find the enthalpy of neutralization of 75.5mL 1.00M aqueous sodium hydroxide with 40.7mL 1.00M hydrochloric acid if after mixing the two solutions the temperature went up 6.2∘C. Report the amount of the limiting reagent in mmol:

 

(enthalpies given: NaOH = -425.61, Cl- = -167.16, H+ = 0)

 

Expert Solution
Step 1

Given that,

Volume of NaOH = 75.5 mL

Molarity of NaOH = 1.00 M

Volume of HCl = 40.7 mL

Molarity of HCl = 1.00 M

Step 2

Now calculate the no.of mole of NaOH

No.of mole-Volume of solution Molarity
mole
No.of mole of N2OH=0.0755L*1.00
L
=0.0755mole
mole
No.of mole of HCl 0.0407L* 1.00-
L
0.0407 mole
Step 3

The reaction is

NaOH+HCl NaCl+H,O
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