For each pair of compounds, circle the compound you expect to have the higher boiling point. Explain your reasoning.(a) (CH3)3C¬C(CH3)3 or (CH3)2CH¬CH2CH2¬CH(CH3)2(b) CH3(CH2)6CH3 or CH3(CH2)5CH2OH(c) CH3CH2OCH2CH3 or CH3CH2CH2CH2OH

For each pair of compounds, circle the compound you expect to have the higher boiling point. Explain your reasoning.(a) (CH3)3C¬C(CH3)3 or (CH3)2CH¬CH2CH2¬CH(CH3)2(b) CH3(CH2)6CH3 or CH3(CH2)5CH2OH(c) CH3CH2OCH2CH3 or CH3CH2CH2CH2OH

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.57P

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

For each pair of compounds, circle the compound you expect to have the higher boiling point. Explain your reasoning.
(a) (CH3)3C¬C(CH3)3 or (CH3)2CH¬CH2CH2¬CH(CH3)2
(b) CH3(CH2)6CH3 or CH3(CH2)5CH2OH
(c) CH3CH2OCH2CH3 or CH3CH2CH2CH2OH

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