For the compound shown, use the RIS configuration given in the compound name to choose che structure with the appropriate wedge-and-dash bonds. S-1-bromo-1-chloroethane Br Br Br Br Br TH CI CI CI CI
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- Classify the following compounds as E and Z structures as applicable:Identify the type of configurational isomerism that exist for each double bond. E or Z(a) Draw the molecular orbital picture for propa-1,2-diene, H2C=C=CH2. Hint: The three-dimensional geometry is shownin the chapter. (b) Draw the MO energy diagram for propa-1,2-diene. What is the HOMO? What is the LUMO?
- Using your model, construct an energy diagram to show the variation in the free energy of the molecule as the FRONT ATOM is rotated CLOCKWISE from 0º to 360º in 60º increments. In your energy diagram, you should clearly show the relative energies of each conformer.which carbons are sp3 and whyIs 2-methyl-2,3-pentadiene chiral? What about 2-chloro-2,3-pentadiene?