For the following basic steps,A2 = A + A (fast; k1, k-1)A + B ---> Products (k2)a. What is the molecularity of the direct step 2 process?b. Using the pre-equilibrium approximation, derive the expression for the predicted rate law for product formation.vs. What is the overall order of the reaction?d. Since k1 is equal to 3.8 x 109 s-1, k-1 is equal to 9.8 x 10^8M-1s-1 and k2 is equal to 2.3 x 10^6M-1s-1, and that the activationenergy for the overall process was determined to be 135.2 kJ mol-1 when measured at 300 K, calculate the overall k value for thereaction at T = 550 K.

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For the following basic steps, A2 = A + A (fast; k1, k-1) A + B ---> Products (k2) a. What is the molecularity of the direct step 2 process? b. Using the pre-equilibrium approximation, derive the expression for the predicted rate law for product formation. vs. What is the overall order of the reaction?

For the following basic steps, A2 = A + A (fast; k1, k-1) A + B ---> Products (k2) a. What is the molecularity of the direct step 2 process? b. Using the pre-equilibrium approximation, derive the expression for the predicted rate law for product formation. vs. What is the overall order of the reaction?

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section11.1: Reaction Rate

Problem 11.2CE: Instantaneous rates for the reaction of hydroxide ion with Cv+ can be determined from the slope of...

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