For the isothermal expansion of a gas into a vacuum,ΔE = 0, q = 0, and w = 0. (a) Is this a spontaneous process?(b) Explain why no work is done by the system duringthis process. (c) What is the “driving force” for the expansionof the gas: enthalpy or entropy?

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section18.2: Dispersal Of Energy: Entropy
Problem 2RC: 2. Which of the following is true for a spontaneous process but not for a nonspontaneous process?...
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For the isothermal expansion of a gas into a vacuum,
ΔE = 0, q = 0, and w = 0. (a) Is this a spontaneous process?
(b) Explain why no work is done by the system during
this process. (c) What is the “driving force” for the expansion
of the gas: enthalpy or entropy?

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