From the given information in the table, calculate: 1)qcontent(J) for part A and B 2) qrxn (J) for part A and B 3) standard enthalpy for part A and B 4) enthalpy of decomposition of NH4CL 5) literature enthalpy of decomposition of NH4Cl

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter5: Principles Of Chemical Reactivity: Energy And Chemical Reactions
Section5.8: Product- Or Reactant-favored Reactions And Thermodynamics
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From the given information in the table, calculate: 1)qcontent(J) for part A and B 2) qrxn (J) for part A and B 3) standard enthalpy for part A and B 4) enthalpy of decomposition of NH4CL 5) literature enthalpy of decomposition of NH4Cl
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Table 1Report): Determination of the enthalpy of decomposition of ammonium chloride
Reactions
Part A
Part B
reagents
HCl
NH3(a9)
NH,Cl)
water
volume (mL) 25
25
50ml
molarity (M) 0.9776
1.30
mass of beaker + NH,CI (g)
31.622
mass of emptied beaker (g)
29.720
mass of NH,CI (g)
1.902
n (mmols) 0.0244
0.0325
0.036
volume (mL)
50 ml
50ml
total
calorimeter
Density (g mL1)
1.00
1.00
Mass = density *
volume = 50*1 = 50 g
content
Mass = density * volume =
50*1= 50g
mass (g)
specific heat, c, (J gl °C!)
4.184
4.184
limiting reagent (yes/no) yes
no
initial temperature (°C) 22 c
21.3 c
final temperature (°C) 28.1 c
19 c
Acootent (J)
Ion (J)
calculated enthalpy of reaction
AH1°
AH,
standard enthalpy
J mmol-1
estigate
Transcribed Image Text:O Search (Alt+Q) erences Mailings Review View Help Table Design Layout Aa v A EE AL T O Fin Emphasis Heading 1 Heading 2 三。 E Rep A Sle Paragraph Styles Editi Table 1Report): Determination of the enthalpy of decomposition of ammonium chloride Reactions Part A Part B reagents HCl NH3(a9) NH,Cl) water volume (mL) 25 25 50ml molarity (M) 0.9776 1.30 mass of beaker + NH,CI (g) 31.622 mass of emptied beaker (g) 29.720 mass of NH,CI (g) 1.902 n (mmols) 0.0244 0.0325 0.036 volume (mL) 50 ml 50ml total calorimeter Density (g mL1) 1.00 1.00 Mass = density * volume = 50*1 = 50 g content Mass = density * volume = 50*1= 50g mass (g) specific heat, c, (J gl °C!) 4.184 4.184 limiting reagent (yes/no) yes no initial temperature (°C) 22 c 21.3 c final temperature (°C) 28.1 c 19 c Acootent (J) Ion (J) calculated enthalpy of reaction AH1° AH, standard enthalpy J mmol-1 estigate
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calculated enthalpy of decomposition of NH.Cle), AH5, (kJ mol-)(as
determined using the equation/answer to Q1 below)
literature enthalpy of decomposition of NH.Clo), AHs, (kJ mol-1)(as
determined in Q2 below)
CHEM 1017 & CHEM 1987
Hess's Law
Additional Questions
1. Express the enthalpy of decomposition of ammonium chloride, AH,, in terms of the four other enthalpies (AH1,
AH2, AH3, AH4) described in the Introduction to this experiment. Use the examples in your textbook for help with
Hess's Law. (Ex. AH, = AHỊ + 2AH2 - AH3 + AH4; this is NOT the answer; use this format).
AH, =
2. List the enthalpies of formation for ammonium chloride (solid), ammonia (gas) and hydrogen chloride (gas)
by referring to the appropriate appendix of your textbook.
Compound
Enthalpy of Formation (AH:) / kJ mol
NH.Cl
-314.4
NH3(2)
-80.2
tigate
Transcribed Image Text:O Search (Alt+Q) ces Mailings Review View Help Table Design Layout O Find - a v Emphasis Heading 1 Heading 2 E Replace A. 三。 A Select Paragraph Styles Editing calculated enthalpy of decomposition of NH.Cle), AH5, (kJ mol-)(as determined using the equation/answer to Q1 below) literature enthalpy of decomposition of NH.Clo), AHs, (kJ mol-1)(as determined in Q2 below) CHEM 1017 & CHEM 1987 Hess's Law Additional Questions 1. Express the enthalpy of decomposition of ammonium chloride, AH,, in terms of the four other enthalpies (AH1, AH2, AH3, AH4) described in the Introduction to this experiment. Use the examples in your textbook for help with Hess's Law. (Ex. AH, = AHỊ + 2AH2 - AH3 + AH4; this is NOT the answer; use this format). AH, = 2. List the enthalpies of formation for ammonium chloride (solid), ammonia (gas) and hydrogen chloride (gas) by referring to the appropriate appendix of your textbook. Compound Enthalpy of Formation (AH:) / kJ mol NH.Cl -314.4 NH3(2) -80.2 tigate
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