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- 4. Compound A has the formula C 8H 8. It reacts rapidly with KMnO 4 to give CO 2 and a carboxylic acid, B (C 7H 6O 2), but reacts with only 1 molar equivalent of H 2 on catalytic hydrogenation over a palladium catalyst. On hydrogenation under conditions that reduce aromatic rings, 4, equivalents of H 2 are taken up and hydrocarbon C (C 8H 16) is produced. What are the structures of A, B, and C.Table 6.4. Oxidation: Reaction with Baeyer’s reagent (cold, dilute, neutral, aqueous KMnO4) Write (+) if the reaction is positive, (-) if negative. SAMPLE OBSERVATIONS +/- cyclohexane cyclohexene benzene toluene acetylene Enumerate the classes of hydrocarbons that are oxidizable by Baeyer’s reagent. ________________________________________________________________________ ________________________________________________________________________ What is the structural feature of these classes of hydrocarbons? ________________________________________________________________________ ________________________________________________________________________Give the balanced equation of acetylene and the following reactions • Combustion • dilute KMnO4 • Ammoniacal CuCl / Ammonical AgNO3
- write the product of the D-gulose reaction by: a. CH3I, Ag2O b. The product in (a), then H3O+ c. The product in (b), then C6H5CH2Cl, Ag2OAn unknown hydrocarbon A with the formula C6H12 reacts with 1 molar equivalent of H2 over a palladium catalyst. Hydrocarbon A also reacts with OsO4 to give diol B. When oxidized with KMnO4 in acidic solution, A gives two fragments. One fragment is propanoic acid, CH3CH2CO2H, and the other fragment is ketone C. What are the structures of A, B, and C? Write all reactions, and show your reasoning.What’s the role of NaBH4 in Oxymercuration-Demercuration of cyclohexene?
- For 20.7 the solutions for part c and d dont seem right. Shouldn't reacting with 1 eq of H2 just take away the C=C bond and not the C=O bond. (H2 reduces C=C selectively to form a ketone according to page 738. Also the both the C=C and C=O bond should be reduced if excess H2 is usedAn unknown hydrocarbon A with the formula C6H12 reacts with 1 molar equivalent ofH2 over a palladium catalyst. Hydrocarbon A also reacts with OsO4 to give diol B. When oxidized with KMnO4 in acidic solution, A gives two fragments. One fragmentis propanoic acid, CH3CH2CO2H, and the other fragment is ketone C. What are thestructures of A, B, and C? Write all reactions and show your reasoning.1. what are the differences between acyclic and cyclic forms in terms of their physical properties? 2. what is the role of vinegar in liquid-liquid extraction?
- Explain this ? "Organic synthesis is the systematic preparation of a compound from areadily available starting material by one or many steps".A saturated hydrocarbon burns in oxygen to give carbon dioxide and water. Approximately twice as much CO2 as H2O (by weight) is produced by this combustion, the actual factor being 2.03. Light induced chlorination of the hydrocarbon by 2.0 equivalents of chlorine gives a mixture of mono-, di- and trichloro compounds, along with small amounts of higher chlorination products. Only one monochloro isomer is formed, but there are two dichloro isomers and three trichloro isomers produced in the reaction. Based on this information, you should be able to identify the hydrocarbon, and draw structural formulas for the chlorinated compounds.Solution:- 3. Determine the amount, in of a (2.20 M s olution of dichloromethane needed to completely react with 15.72g cyclohexene to give 1,2-dibromocuclohexanw. Assume 12% excess is needed in order to react completely. a . How much 1,2 -dibromocyclohexane would theoretically be produced ? c. How many ML of the 2.20 M Br2 solution are required?