Give a suitable chemical reaction to distinguish between a primary and a secondary amine. Suggest one way of Increasing the basicity of an amine and give a specific example of its application.

Answered: Image /qna-images/answer/6ffa3fc8-abd4-4130-b0b3-b546b674ce1f.jpg

Answered: Give a suitable chemical reaction to…

Science

Chemistry

Give a suitable chemical reaction to distinguish between a primary and a secondary amine.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.39P

See similar textbooks

Related questions

Q: An amine of unknown structure contains one nitrogen and nine carbon atoms, as well as at least one…

A: 13C -NMR of the compound gives 5 signals between 20 and 60 ppm. This indicates there are 5 types of…

Q: Give reasons :(i) Electrophilic substitution in aromatic amines takes place more readily than…

A: i) Due to delocalization of lone pair of electrons on N-atom of NH2 group in aromatic ring aromatic…

Q: Differentiate between imine and enamine formation?

A: Imine and enamine are the compounds that can be prepared through the reaction of an aldehyde or…

Q: Which of the following compounds is not a heterocyclic amine? a. pyridine O b. imidazole O c. purine…

Q: (ii) Primary amines can be prepared from amides by Hoffmann's degradation. (a) Write a general…

A: When an amide is treated with bromine in an aqueous or ethanolic solution of sodium hydroxide,…

Q: Suggest one way of Increasing the basicity of an amine and give a specific example of its…

A: Basicity of amine can be increased by increasing the electron donating group like CH3 , C2H5 ,C3H7…

Q: Explain the effect of acid on the solubility of water-insoluble amines. Support your answer using…

A: "Like dissolves like" is the thumb rule for dissolution of solute in solvent. This means ionic…

Q: Help

A: The given amine is a secondary amine. Secondary amine reacts with a ketone in the presence of acid…

Q: Write structural formulas for all the amines of molecular formula C4H11N. Give an acceptable name…

A: The structural formulas for all the amines of molecular formula C4H11N has to be drawn.

Q: Suppose you were given the structural formula of compound B but only the molecular formulas for…

Q: By functional group interconversion, which of the following compounds is not a good starting…

Q: Predict the major products formed when the following amines undergo exhaustivemethylation, treatment…

A: The formation of major product, when the given amine undergoes exhaustive methylation, treatment…

Q: Which of the following compounds is WILL NOT form an amide in a reaction with a carboxylic acid…

Q: Give the amine classification for now-synephrine and methamphetamine .

A: The structure of neo-synephrine and methamphetamine are as shown below.

Q: Show how to convert amines to other functional groups, and devise multistepsyntheses using amines as…

Q: Draw the structure of the product that will be formed when each of the following amines reacts with…

Q: Features of the structure of imino acids. Formation of amides from amino acids.

A: Amino acids

Q: Considering Hinsberg's Method to determine, 1°, 2°, 3° amines. Draw the structure of the products…

A: The outcomes for the given reactions are heavily decided by the presence of H-atom on the nitrogen.

Q: A. Structure, Classification, and Solubility of Amines Asiline N Methylanilior Triethy lamine L…

A: ANILINE Condensed structural formula = C6H7N Classification: Primary Solubility - 3.6g/100mL at 20…

Q: What are the types of coupling reaction available for amines? Which type will produce dyes?

A: Coupling reactions available for amines 1.C-N cross coupling reaction 2.Buchwald -Hartwig cross…

Q: The amines are organic weak bases which are nitrogen-containing. In the early days of organic…

A: (1) Generally, an alkaloid contains at least one nitrogen atom in an amine-type structure—i.e., one…

Q: Propose a method that can be used to classify amines. Explain how the test is performed and what are…

Q: neutral because of the polarity are unique as they do not behave like any of the other amines…

A: Basicity is tendency to available lone pair of electrons for an acid.

Q: Is it possible to classify primary, secondary, and tertiary amines through the quinhydrone test?…

Q: Account for the experimental behavior of each class of amines (primary, secondary and tertiary)…

A: A question based on organic chemistry, which is to be accomplished.

Q: Reactions of aldehydes and ketones with amines and amine derivatives a. Draw reaction with a primary…

A: Amines is considered as organic derivatives of ammonia where alkyl groups replace the hydrogen atoms…

Q: -sopropyl pro-pylamine -tripopylamine -benzylmethylamine -benzyldimethylamine -propylamine…

A: Amines can be classified depending on the number of carbon atoms of the alkyl/aryl group bonded to…

Q: In a series of substituted amines (1-aminobutane, 2-aminobutane, N,N- diethylamine, and t-butyl…

A: Given: Substituted amines To find: Order of decreasing boiling point is based on which criteria…

Q: : Generalized structural formela for secondary amine, structural forymeda for amide modecular…

A: Interpretation - To illustrate the generalize structure formula for the secondary amine , structure…

Q: Background of amines compounds and explain hinsberg test of amines

A: Solution : Amines are derived from ammonia. They are compounds with functional groups containing…

Q: Predict the products from the reactions of the following amines with sodium nitrite indilute HCl.(a)…

A: The product from the reactions of the following amines with sodium nitrite in dilute HCl has to be…

Q: Prepare CH3COOC2H5, ethyl acetate, using ethyl alcohol. Write the chemical reaction. The pain…

A: Esters can be prepared by alcohols and carboxylic acid in the presence of an acid catalyst using…

Q: 1,4-Diazabicyclo[2.2.2]octane (abbreviated DABCO) is a tertiary amine that catalyzes…

A: The nitrogen atom of DABCO attacks the carbonyl carbon of ester group which makes the alkoxy group a…

Q: Compare the reactivity of the primary amine to secondary amines towards the synthesis of amides.…

Q: An amine found in the brain wherein deficiency of these results to Parkinson's disease. epinephrine…

Q: I) Sketch a stepwise mechanism for the reaction of secondary amine with an acid chloride to generate…

A: Given, Reactant 1 = Secondary amine Reactant 2 = Acid chloride Mechanism of the reaction = ?

Q: Which of the following alcohols will give a carboxylic acid product when reacted with K2Cr2O7?…

Q: Compare the table below by giving the structure and name of a primary (10), secondary(20), and…

A: Amines can be primary, secondary or tertiary and is based upon the number of alkyl groups on the…

Q: Explain and describe the objective for Qualitative analysis of amines and amine Unknown.

Q: Why are the boiling points of tertiary amines lower than those of corresponding primary and…

A: Amines are organic compounds that contain nitrogen atoms with a lone pair. Basically, they are…

Q: Classify amines as aliphatic or aromatic amines (by writing the aromaticity rule).

A: By using the rule of aromatic we can classify the amines as aromatic amines and aliphatic amines.

Q: Propose structures for amines that fit these descriptions:(a) A secondary amine with formula…

A: When one or more H atom is replaced in ammonia by alkyl or aryl group are called amines, because…

Q: The chemical reaction in determining amine nitrogen by formular titration is based on the…

A: We have to tell the chemical reaction in determining the amine nitrogen by the formula titration is…

Q: Predict the major products formed when the following amines undergo exhaustivemethylation, treatment…

A: Elimination reactions: Organic reactions contain the removal of a group of atoms from a molecule by…

Question

Give a suitable chemical reaction to distinguish between a primary and a secondary amine.

Suggest one way of Increasing the basicity of an amine and give a specific example of its application.

Definition Definition Organic compounds with a nitrogen atom having a lone pair of electrons on it. Amines are derived from ammonia (NH 3 ), wherein hydrogen atoms are substituted by an aryl or alkyl group.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Suggest one way of Increasing the basicity of an amine and give a specific example of its application.
Primary amines can be prepared from amides by Hoffman's reaction. Write a general equation for the reaction and give reagents with reaction conditions for this reaction. What property of amines is responsible for them being basic. Suggest one way of Increasing the basicity of an amine and give a specific example of its application.
Write structural formulas for all the amines of molecular formula C4H11N. Give an acceptable name for each one, and classify it as a primary, secondary, or tertiary amine.
Rationalize the electronic effects responsible for the basicity of amines
The compound acetophenone has a very similar molar mass to that of benzoic acid and benzamide. However, acetophenone has a much lower m.p. (20 °C) than both such that, by contrast, it is a liquid at room temperature. By considering intermolecular forces and comparing functional group structure, account for this big difference in physical properties.
(a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.
Rank the following amines based on basicity Rationalize the electronic effects responsible for the basicity of amines
Which of these amines would produce the salt with the highest melting point if mixed separately with hydrochloric acid (HCl)? Based on the structure and properties of the resulting ammonium salts, explain your reasoning
In addition to HCl, what is the product of the reaction of aprimary amine with an acid chloride? Draw the structureof that product and describe its features
Show how to convert amines to other functional groups, and devise multistepsyntheses using amines as starting materials and intermediates
Explain the observed difference in the pKa values of the conjugate acids of amines A and B.
Following is a series of anorexics (appetite suppressants). As you study their structures, you will surely be struck by the sets of characteristic structural features Q. Knowing what you do about the synthesis of amines, including the Ritter reaction , suggest a synthesis for compound