Given data: The concentration of hydrofluoric acid = 0.25 M The volume of hydrofluoric acid = 250 mL The pH of the solution is 3.50 Mole calculation: We know that, pk = -log K₁ The K₂ for hydrofluoric acid is 6.8 x 10-4 The moles of hydrofluorie acid that is needed can be calculated using the Henderson-Hasselbalch equation as follows, pH= pk + log- [conjugate base] [weak acid] [Buffer. base] pH= pk + log- [Buffer. acid] [F] 3.50= -log K + log (HF) = -log(6.8 x 10-¹) + log- = 3.167 +log[0.25] -log[HF] log[HF]= 3.167 -0.602 - 3.50 -0.9351 [HF] = 0.1161 M Therefore, the concentration of hydrofluoric acid is 0.1161 M The mole of hydrofluoric acid is calculated as follows, Concentration=; mole Total volume (0.25 M) [HF] How did mol HF=Concentration x Total volume = 0.1161 x 0.250 L = 0.029 mol Therefore, the number of moles required is 0.029 mol they get this?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 103AP
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Given data:
The concentration of hydrofluoric acid = 0.25 M
The volume of hydrofluoric acid = 250 mL
The pH of the solution is 3.50
Mole calculation:
We know that,
pk = -log K₁
The K₁ for hydrofluoric acid is 6.8 x 10-4
The moles of hydrofluorie acid that is needed can be calculated using the Henderson-Hasselbalch equation
as follows,
[conjugate base]
[weak acid]
pH= pk + log.
pH= pk + log.
3.50= -log K + log;
[Buffer, base]
[Buffer. acid]
[F]
(HF)
(0.25 M)
= -log(6.8 x 10-4) + log- (HF]
= 3.167 +log[0.25] -log[HF]
log[HF]= 3.167 -0.602 - 3.50
-0.9351
[HF] = 0.1161 M
Therefore, the concentration of hydrofluoric acid is 0.1161 M
The mole of hydrofluoric acid is calculated as follows,
Concentration =
How did
mole
Total volume
mol HF=Concentration x Total volume
= 0.1161 x 0.250 L
= 0.029 mol
Therefore, the number of moles required is 0.029 mol
they get this?
Transcribed Image Text:Given data: The concentration of hydrofluoric acid = 0.25 M The volume of hydrofluoric acid = 250 mL The pH of the solution is 3.50 Mole calculation: We know that, pk = -log K₁ The K₁ for hydrofluoric acid is 6.8 x 10-4 The moles of hydrofluorie acid that is needed can be calculated using the Henderson-Hasselbalch equation as follows, [conjugate base] [weak acid] pH= pk + log. pH= pk + log. 3.50= -log K + log; [Buffer, base] [Buffer. acid] [F] (HF) (0.25 M) = -log(6.8 x 10-4) + log- (HF] = 3.167 +log[0.25] -log[HF] log[HF]= 3.167 -0.602 - 3.50 -0.9351 [HF] = 0.1161 M Therefore, the concentration of hydrofluoric acid is 0.1161 M The mole of hydrofluoric acid is calculated as follows, Concentration = How did mole Total volume mol HF=Concentration x Total volume = 0.1161 x 0.250 L = 0.029 mol Therefore, the number of moles required is 0.029 mol they get this?
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