Given data: The concentration of hydrofluoric acid = 0.25 M The volume of hydrofluoric acid = 250 mL The pH of the solution is 3.50 Mole calculation: We know that, pk = -log K₁ The K₂ for hydrofluoric acid is 6.8 x 10-4 The moles of hydrofluorie acid that is needed can be calculated using the Henderson-Hasselbalch equation as follows, pH= pk + log- [conjugate base] [weak acid] [Buffer. base] pH= pk + log- [Buffer. acid] [F] 3.50= -log K + log (HF) = -log(6.8 x 10-¹) + log- = 3.167 +log[0.25] -log[HF] log[HF]= 3.167 -0.602 - 3.50 -0.9351 [HF] = 0.1161 M Therefore, the concentration of hydrofluoric acid is 0.1161 M The mole of hydrofluoric acid is calculated as follows, Concentration=; mole Total volume (0.25 M) [HF] How did mol HF=Concentration x Total volume = 0.1161 x 0.250 L = 0.029 mol Therefore, the number of moles required is 0.029 mol they get this?
Given data: The concentration of hydrofluoric acid = 0.25 M The volume of hydrofluoric acid = 250 mL The pH of the solution is 3.50 Mole calculation: We know that, pk = -log K₁ The K₂ for hydrofluoric acid is 6.8 x 10-4 The moles of hydrofluorie acid that is needed can be calculated using the Henderson-Hasselbalch equation as follows, pH= pk + log- [conjugate base] [weak acid] [Buffer. base] pH= pk + log- [Buffer. acid] [F] 3.50= -log K + log (HF) = -log(6.8 x 10-¹) + log- = 3.167 +log[0.25] -log[HF] log[HF]= 3.167 -0.602 - 3.50 -0.9351 [HF] = 0.1161 M Therefore, the concentration of hydrofluoric acid is 0.1161 M The mole of hydrofluoric acid is calculated as follows, Concentration=; mole Total volume (0.25 M) [HF] How did mol HF=Concentration x Total volume = 0.1161 x 0.250 L = 0.029 mol Therefore, the number of moles required is 0.029 mol they get this?
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 103AP
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