Given the following: A cell SCE // Ag2CrO4 (saturated), CrO42- (xM) /AG is used for the determination of pCrO4- (ESCE = -0.244 V at 25 C). The half reaction at indicator electrode is: Ag2CrO4(s) + 2e-   2 Ag(s) + CrO42- (E0 = +0.446 V) What is pCrO4, given the cell potential of 0.402? What type of indicator electrode is Ag in this situation?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.21QAP
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Given the following:

 

A cell SCE // Ag2CrO4 (saturated), CrO42- (xM) /AG is used for the determination of pCrO4- (ESCE = -0.244 V at 25 C).

 

The half reaction at indicator electrode is: Ag2CrO4(s) + 2e-   2 Ag(s) + CrO42- (E0 = +0.446 V)

 

  1. What is pCrO4, given the cell potential of 0.402?
  2. What type of indicator electrode is Ag in this situation?
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