3. Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl groupand form chelate ringsbonded through both the N and one of the O atoms. Drawstructures for all possible isomers of tris(glycinato)cobalt(III).4. Sketch structures of all isomers of M(AB)3, in which ABis a bidentate unsymmetricalligand, and label the structuresfacor mer.5. Sketch all isomers of the following. Indicate clearly eachpair of enantiomers.i. [PI(NH;);Cls]"ii. [Co(NH,);(H,O),CH]*iii. [Co(NH,):(H;0),BICI)iv. [CrH,O),BrCinv. [Pt(en):Cla)**vi. [Pt(bipy),BrC1}*How many possible isomers are there of an octahedral complex having the formulaM(ABC)(NH,H;O)Br, where ABC is the tridentate ligandH,N-C,H,-PH-C,H-ASH2? How many of these consist of pairs of enantiomers?Sketch all isomers, showing clearly any pairs of enantiomers. The tridentate ligand maybe abbreviated as N-P-As for simplicity.

These are the structures of the two possible isomers of tris(glycinato)cobalt III. The first one is…

Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group and form chelate ringsbonded through both the N and one of the O atoms. Draw structures for all possible isomers of tris(glycinato)cobalt(III).

Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group and form chelate ringsbonded through both the N and one of the O atoms. Draw structures for all possible isomers of tris(glycinato)cobalt(III).

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 105QRT

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Concept explainers

Stereochemistry and Isomerism

Stereochemistry deals with the three-dimensional structure and properties of molecules. It explains the arrangement of atoms and their manipulation within a molecule in a 3D structure. Stereochemistry can be dealt with all types of molecules. Based on the stereochemistry of a molecule, the physical and chemical properties of the molecules vary.

Question

100%

3. Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group
and form chelate ringsbonded through both the N and one of the O atoms. Draw
structures for all possible isomers of tris(glycinato)cobalt(III).
4. Sketch structures of all isomers of M(AB)3, in which ABis a bidentate unsymmetrical
ligand, and label the structuresfacor mer.
5. Sketch all isomers of the following. Indicate clearly eachpair of enantiomers.
i. [PI(NH;);Cls]"
ii. [Co(NH,);(H,O),CH]*
iii. [Co(NH,):(H;0),BICI)
iv. [CrH,O),BrCin
v. [Pt(en):Cla)**
vi. [Pt(bipy),BrC1}*
How many possible isomers are there of an octahedral complex having the formula
M(ABC)(NH,H;O)Br, where ABC is the tridentate ligand
H,N-C,H,-PH-C,H-ASH2? How many of these consist of pairs of enantiomers?
Sketch all isomers, showing clearly any pairs of enantiomers. The tridentate ligand may
be abbreviated as N-P-As for simplicity.

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