Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s?3d6 Cdº: [Kr]5s²4d10 Pt0: [Xe]6s25d® A. [FeBr2Clz]2- B. [Cd(NH3)2(H2O)212+ O C. [PtBr2(NH3)2] O D. All of the above.

Q: The CFSE for octahedral [CoCl]ª¯ is 18,000 cm1. The CFSE for tetrahedral [CoCl4]²¯ will be.. а.…

A: When the ligands are same in Octahedral and Tetrahedral then the CFSE of Octahedral and Tetrahedral…

Q: (c) Design syntheses of (i) cis and (ii) trans isomers of [PtCl₂(CN)(NH3)], using K₂PtCl4, KCN and…

A:

Q: The following organometallic compounds are stable and has a second row transition metal at its…

A: Concept:  18-electron rule: The 18-electron Rule is a rule which predicte rhe stability of a…

Q: How is ligand bound to a protein? List the physical forces?

A: The forces through which one ion or molecule is bounded to another ion or molecule are termed as…

Q: addition of S2- ion to Fe(OH)2(s) results in the formation of FeS(s). Explain why the addition of…

A:

Q: 28. The three "d" orbitals that have higher energy in an octahedral field c) dz2 and dx2 - y2 a) dxy…

A:

Q: 26. The molecular shape of the atoms in PCla1 is best described as (A) tetrahedral (C) see-saw (B)…

A: The shape of the molecule can be predicted with the help of the VSEPR theory. The shape is predicted…

Q: Why should the trans,trans isomer be the thermodynamically most stable one?

A: To explain why trans isomer is thermodynamically most stable.

Q: Consider a d8 compound (like Pt(II)). What is more likely to form a 4-coordinate or a 6-coordinate…

A: Valence Bond Theory (VBT) Crystal Field Theory (CFT) Considers formation of covalent bonds…

Q: 94. Carbon in cast iron 1. lowers its melting 2 increases its hardness and decrease its ductility 3.…

A: 94. D. Only 3 is correct.  Carbon in cast iron decreases its hardness and increases its ductility.…

Q: The following organometallic compounds are stable and has a second row transition metal at its…

A: Organometallic compounds are those chemical compounds which contain at least one metal-carbon bond.…

Q: 2. Which of the following pair of complexes will have the lowest average CO IR stretching frequency.…

A: Concept: If there are more electron donating ligands in the complex, the more electron rich the…

Q: Which of the following orders is correct for Tolman cone angles for PR3 ligands? а. РМез > РET3 b.…

A: Tolman Cone angle          → Depends on the basis of steric size . Layer the size layer is the…

Q: The following structure is? Time left a. cannot be determined O b. none of the other answers С. cis…

A: The given structure is cycloalkane compound and the name of the compound is 1,2-dimethyl…

Q: WRITE A NOTE ON OPTICAL ISOMERIM (ACTIVITY)?

A: Given: Write a note on optical isomerism

Q: It is observed that the substitution reactions of square plane complexes generally follow the SN2…

A:

Q: For each pair of molecules below, choose the one you would predict to be more stable and briefly…

A:

Q: 2048C 2148 Sc which is more stable or

A:

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: 32. Between Pbl2 (Ksp = 7.9x10-) and PbC204 (Ksp 8.5x10-), which is %3D more soluble in water? Pbl2…

A:

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s²3d6 Cdº: [Kr]5s²4d10 Ptº:…

A: A multiple choice question based on coordination complex, which is to be accomplished.

Q: D) Identify the compounds that are not chiral. Br Br B D Br

A: The given compounds contain a cyclohexane ring. The carbon atom attached to four different groups…

Q: In the inorganic chemistry laboratory, we synthesized the compound K(Cr(C2O4)2(H2O)2).2H2O using…

A: During the production of K(Cr(C2O4)2(H2O)2).2H2O using potassium dichromate, oxalic acid dihydrate…

Q: A complex of formula [M(N = CCH3)6](NO3)2, in which the M(II) ion is that of a firstrow (3d)…

A: Answer: With the help of Magnetic moment, find out the number of unpaired electrons central metal…

Q: 3. Which complex shows lower C-O stretching frequency, [Ni(acac)2(H2O2 or [Ni(acac)2]? Explain.

A:

Q: How is the compound [CrCl2(H2O)4]Cl.2H2O named according to the Ewen-Basset system? A.…

A:

Q: (a) Based on the compound, deca-1,3,5,7,9-pentaene: (i) Give the total number of TT molecular…

A: Hello. Since your question has multiple sub-parts, we will solve first three sub-parts for you. If…

Q: (d). When the bidentate neutral ethylenediamine (en, -NH2CH2CH2NH2-) reacts with Co(lII) chloride,…

A:

Q: The organometallic chemistry of magnesium and zinc is often considered to be very similar. However,…

A: Answer - Organometallic compound - Organometallic compounds are defined as compounds containing a…

Q: 54. In the octahedral complex Co(NH2CH2CO2)3, each glycinate ion NH2CH2CO2¯ binds to cobalt through…

A: This question is related to stereochemistry. Stereoisomers are the molecules having the same…

Q: If A, B, C, and D are four - electrically neutral - different single-tooth substituents, what kind…

A: To show the kind of isomerism shown by the tetrahedral complex [ZnABCD]2+, where A, B, C and D are…

Q: Since the Coomassie Brilliant Blue G-250 is a highly (basic, acidic) dye, it cannot be used for…

A: The structure of Coomassie brilliant blue G-250 is:

Q: [Co(CN):(OH;)J* + [Co(NH3)s(NCS)}* = [Co(CN):(SCN)]* + [Co(OH,);F* 3. Explain why, in the products…

A:

Q: Write down the formula of : Tetraamineaquachloridocobalt(III) chloride.

A: The given coordination complex is tetraamineaquachloridocobalt(III) chloride.

Q: [Co(CN),(OH;)]* + [Co(NH3)s(NCS)* = [Co(CN):(SCN)]* + [Co(OH,);}** 3. Explain why, in the products…

A:

Q: Which of teh following compounds has the standard formation of free energy deltaGf=0? a. CO(g) b.…

A: Answer: When any element is in its standard state at room temperature and 1 atm pressure, its…

Q: Which option indicates, in order, whether the following compounds obey the effective atomic number…

A: ***Note: Since you have posted a question with multiple subparts, we will solve the first three…

Q: Write all the isomers of [PtCl(CO)(PMe3)(C2H4)]+ and use the trans directing effect of ligands to…

A: Isomers of [PtClCOPMe3C2H4]+

Q: Calculate in units of deltaₒ, the LFSE for the octahedral ions below in their high-spins state.…

A: LFSE (Ligand Field Stabilisation Energy) is the measure of the stability of the complexes.

Q: What chemical change is responsible for the yellow solution observed during the qualitative test for…

A:

Q: 3. (a) Based on the compound, deca-1,3,5,7,9-pentaene: (0) Give the total number of TT molecular…

A: Frontier molecular orbital theory is most widely used in Pericyclic reactions. The FMO analysis is…

Q: i, d electron configuration ii crystal field theory summary i high/low-spin assignment based on…

A: (i)d electron configuration  Electronic configuration = (n-1)d1-10ns1-2 the element of d block have…

Q: draw the alpha and beta isomers of tris(acetylacetonato)chromium(iii) and label them

A:

Q: Classify the following reactions as oxidative addition, reductive elimination, (1,1 / 1,2)migratory…

A:

Q: raw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Since you have posted more than 1 question, we are doing 1st one for you. To do the rest repost the…

Q: Which of the following salts gives the following Ksp expression? Ksp = 108s5 a. Sn(OH)4 B.…

A: a. Sn(OH)2 Sn(OH)2 (s) ⇌ Sn2+ (aq) + 2 OH- (aq)                        s                   2s…

Q: Which of the following is most likely tetrahedral in geometry? a.…

A: For tetrahedral complex compound should have four coordination number and should have SP3…

Stereochemistry and Isomerism

Stereochemistry deals with the three-dimensional structure and properties of molecules. It explains the arrangement of atoms and their manipulation within a molecule in a 3D structure. Stereochemistry can be dealt with all types of molecules. Based on the stereochemistry of a molecule, the physical and chemical properties of the molecules vary.