h) Find Moles of Reaction (Mg is the limiting reagent, so calc how many moles of Mg reacted from grams of Mg) 9rxn O. 453 ng 0.23 25g * /mol mg 2.168.3- 3 i) AH = qrxn /moles 240319 mg 0.0095 39 mb) Mga y counts A -06453 kJ A5111 spl) + past moles: 0.009564 mol Mg 4 AHrxn2-4104 kj/mol =-47.36 kj/mol 1.76

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
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h) Find Moles of Reaction (Mg is the limiting reagent, so calc how many moles of Mg
qrxn Ou 453
reacted from grams of Mg)
Mg Do 23 25g * Imol mg
24031g mg
i) AH = qrxn /moles
en
-06453 k
0.0095 64 mulig
Sun Ve NG-
NAVNE
1038
10 polecela da pra caster's
CFIGHT CAN HOS
(0) NO
So,
TOMISSIS
= 0.009539 mabl Mg
moles: 0.009564 mol Mg
pallpAHxn2-4164 kj/mol
= -47.36 kJ/mol
dal second
CASTEMT CASHMus
Content
CAJHOST) estis
cont
MY OH 7 ) M
tad po tom 21.06's ton/10
HAR-cscborg HAS A
COROEST
139
Transcribed Image Text:h) Find Moles of Reaction (Mg is the limiting reagent, so calc how many moles of Mg qrxn Ou 453 reacted from grams of Mg) Mg Do 23 25g * Imol mg 24031g mg i) AH = qrxn /moles en -06453 k 0.0095 64 mulig Sun Ve NG- NAVNE 1038 10 polecela da pra caster's CFIGHT CAN HOS (0) NO So, TOMISSIS = 0.009539 mabl Mg moles: 0.009564 mol Mg pallpAHxn2-4164 kj/mol = -47.36 kJ/mol dal second CASTEMT CASHMus Content CAJHOST) estis cont MY OH 7 ) M tad po tom 21.06's ton/10 HAR-cscborg HAS A COROEST 139
3) Calculate qn and AH for the 1 M HC1/Mg Ribbon Rxn.
The amount of energy the reaction gives off (-qrnx) is given to the solution in the calorimeter
and the calorimeter itself. This means that -qrxn is equal to the amount of energy the solution
absorbed (qso) and the energy the calorimeter absorbs (qeal) Mathematically, the equation that
describes this is:
-qrxn (qsol +qcal) or
qrxn-[(msol X Csol X AT) + (Ccal X AT)]
Note that Tmax is the final temperature for all species when calculating the AT. To convert
volume of the solution to g of solution use the following: the density of 1 M HCl is 1.01 g/mL.
The specific heat of the solution is 4.04 J/g °C.
Calculate the following:
qrxn=-(qsol+qcal)
a) Volume of HCl(from data)
VHCI 100..
b) Find mass of the solution using the mL of HCl and the density given above
100.0 mL x 1001 g/mL = 10lg g
c) Find the initial temp of the HCI (from data)
d) Find the maximum reaction temp from data
He) Find AT
(AT=Tmax-Tinitial)
33.2°C -20.2°C =
g) Convert qrn to kJ
lks
-4535
1000)
msol: 10.09
*H0all Joe.de
Tinital: 20-2°C
Tmax: 33.22
f) Find qrxn
2009 (9rxn=- [(msol X Csol X AT) + (Ccal X AT)]) where Csol is given above, and Ccal is
calculated in part 1.
ΔΤ: [3.00 c°
-[(1010gx 4:04 J/g °C x 13.006) + (23602 j/2 x 13.00) = -452.78
-153.92 +-299.26
9rxn-4531
(should be negative)
0.453k
138
Transcribed Image Text:3) Calculate qn and AH for the 1 M HC1/Mg Ribbon Rxn. The amount of energy the reaction gives off (-qrnx) is given to the solution in the calorimeter and the calorimeter itself. This means that -qrxn is equal to the amount of energy the solution absorbed (qso) and the energy the calorimeter absorbs (qeal) Mathematically, the equation that describes this is: -qrxn (qsol +qcal) or qrxn-[(msol X Csol X AT) + (Ccal X AT)] Note that Tmax is the final temperature for all species when calculating the AT. To convert volume of the solution to g of solution use the following: the density of 1 M HCl is 1.01 g/mL. The specific heat of the solution is 4.04 J/g °C. Calculate the following: qrxn=-(qsol+qcal) a) Volume of HCl(from data) VHCI 100.. b) Find mass of the solution using the mL of HCl and the density given above 100.0 mL x 1001 g/mL = 10lg g c) Find the initial temp of the HCI (from data) d) Find the maximum reaction temp from data He) Find AT (AT=Tmax-Tinitial) 33.2°C -20.2°C = g) Convert qrn to kJ lks -4535 1000) msol: 10.09 *H0all Joe.de Tinital: 20-2°C Tmax: 33.22 f) Find qrxn 2009 (9rxn=- [(msol X Csol X AT) + (Ccal X AT)]) where Csol is given above, and Ccal is calculated in part 1. ΔΤ: [3.00 c° -[(1010gx 4:04 J/g °C x 13.006) + (23602 j/2 x 13.00) = -452.78 -153.92 +-299.26 9rxn-4531 (should be negative) 0.453k 138
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