HC(g) can react with methanol vapor, CH;OH(8), to produce CH;CI(g), as represented by the following equation. CH;OH(g) + HCI(g) 2 CH;CI(g) + H2O(g) K, = 4.7x 10° at 400 K CH,OH(g) and HCI(g) are combined in a 10.00 L sealed reaction vessel and allowed to reach equilibrium at 400 K. The initial partial pressure of CH,OH(8) in the vessel is 0.250 atm and that of HCI(g) is 0.600 atm. (i) Does the total pressure in the vessel increase, decrease, or remain the same as equilibrium is approached? Justify your answer in terms of the reaction stoichiometry.

Introduction to General, Organic and Biochemistry
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Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
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HC(g) can react with methanol vapor, CH;OH(8), to produce CH;CI(g), as represented by the following
equation.
CH;OH(g) + HCI(g) 2 CH;CI(g) + H2O(g)
K, = 4.7 x 10° at 400 K
CH,OH(g) and HCI(g) are combined in a 10.00 L sealed reaction vessel and allowed to reach equilibrium at
400 K. The initial partial pressure of CH,OH(8) in the vessel is 0.250 atm and that of HCI(g) is 0.600 atm.
(i) Does the total pressure in the vessel increase, decrease, or remain the same as equilibrium is
approached? Justify your answer in terms of the reaction stoichiometry.
Transcribed Image Text:HC(g) can react with methanol vapor, CH;OH(8), to produce CH;CI(g), as represented by the following equation. CH;OH(g) + HCI(g) 2 CH;CI(g) + H2O(g) K, = 4.7 x 10° at 400 K CH,OH(g) and HCI(g) are combined in a 10.00 L sealed reaction vessel and allowed to reach equilibrium at 400 K. The initial partial pressure of CH,OH(8) in the vessel is 0.250 atm and that of HCI(g) is 0.600 atm. (i) Does the total pressure in the vessel increase, decrease, or remain the same as equilibrium is approached? Justify your answer in terms of the reaction stoichiometry.
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