Which of the following reactions form the product shown on hydrolysis? R=alkylHO CH2co,R2 CH;MgBr +CHHO, CH:CHLI +PhPhOHO 2 CH;CH MgBr + PhCO,R= H;CH2C-CH CH3Phperiodinane CHOHO,CHCI2

In this question, we want to identify the right product means Product shown on right side is right…

Answered: HO CH, COR 2 CH;MgBr + CH HO, CH: CHLI…

Science

Chemistry

HO CH, COR 2 CH;MgBr + CH HO, CH: CHLI + Ph Ph OH O 2 CH;CH MgBr + PhCO,R H;CH2C-CH CH3 Ph Loo CCHO periodinane CHCI2

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions

Section21.SE: Something Extra

Problem 54AP: The following reactivity order has been found for the saponification of alkyl acetates by aqueous...

See similar textbooks

Related questions

Q: Lalaulate the eH of a 3 lox1D M la/OH),s Selution.CafoH)is. isa strory buse.

Q: Br CH₂ a. 95-48 and 2 3 Br CH₂ C1- C2- C3- C4- Related- b. Me 1 Me OH and Et 2 Et OH C1- C2-…

Q: H2N-CH-c-OH 4. CH3 Neutral/acidic/ basic Polar/ non-polar Hydrophobic/hydrophilic. H2- N -сн—с—оН…

A: Side chain in an amino acid determines its nature (acidic, basic or neutral), polarity and…

Q: NaSCH3, DMSO, r.t. ...|CI е. -D NaOCH3, HOCH3 heat H f. H Br NaOCH3, HOCH3 heat DIl Ph Ph d.

Q: What is the hybridization of the nitrogen in aniline? 1. The nitrogen is sp2 hybridized. 2. The…

Q: Acrymaide (2-propan -I amide) is an organic conipound that is common_component of electrophretic…

A: A bond is said to be polar, if the bond is between two atoms having significant difference in…

Q: Q 20 Complete the following reaction: NC. NaOCH3 ELOH Ph NC Ph Ph CN CN Ph Ph NC

Q: но H H. H. он + 3H20 -C H. H H H. H. 1. H,0' H-C- H-C -C- -C- -C H 2. H H но †N\CH»¾Ñ-Č(CH»),T+ 2n…

A: Polymerization are classified in chain polymerization, step growth polymerization. Now chain…

Q: A) Base 1 is EtONa and base 2 is KOC(CH3)3 B) Both bases are KOC(CH3)3 C) Both bases are EtONa D)…

A: Kinetically controlled product: Product which form according to rate of reaction and depends on…

Q: What steps would you need to take to calculate the pKa1 and pKa2 of something? For example:…

A: We can use acid-base titration experiment to find the pKa value of any acid: monoprotic, diprotic,…

Q: Classify the following alcohols accordingly in sequence HO, OH а) b) c) 2°, 20, 1° 1º,2°, 30 1°, 30,…

Q: O2N. OH NaH TCI of H2SO4 HNO3 H,SO4 HNO3

Q: Account for the fact that one carboxyl group is a considerably stronger acid than the other carboxyl…

Q: Q#1 Ehyl Acetate Target Molecule 1.) NaOEt (1 equi). EOH 1.) NaOE (2 equi) 2) CH (2equv) a.) 2) H0…

Q: OH HH HHHH HHHH HHE I I II IILI Н-о—с-с -С-с-с-с-с-с-С-С-с-с-с- HHH I | | L -с-с-с-—С-н H H HHH H H…

A: Given carboxylic acid is saturated fatty acid

Q: The cis- and trans- isomers shown below have the same physical properties. НООС, H. COOH C. COOH .C.…

Q: Propose a reagent for the conversion of B to C.

A: The given compound B contains a carbonyl carbon. The desired compound C contains an alcohol group in…

Q: What is the molecular formula of this psychoactive compound? (CH3 CH₂)2NC H ******* ****** HN A.…

Q: Sort the following in the increasing of stability. give reasons for your answers. M-CH3, M-CF3,…

Q: 5. CH,COОН + CH3CH2OCOCH3 H20 + -COCH3 6. (6а) (6b)_- + H2O -СООН 7. (7a)_ + 2 NaOH _(7b) + NazCOз.…

A: Organic reaction mechanisms:

Q: a. m-chloroethylbenzene I.CH.CCI AICI, ZaHg) H,NNH, or HCL, A HO, A CH CH,CH, CH, 2 HO or H Pd/C CI…

A: We have find out mechanism for both reactions of a and b.

Q: e systematic names: * CH3CH2-0-CH2CH3 CH3-CH=CH2-COOH Ph-COOCH3 Ph-OH (CH3)2 CH-CH2OH

A: Since you have asked multiple question, we will solve the first question for you.If you want any…

Q: carbonate ion hydrogen carbonate ion HCO3 acetate ion CH3COO K = 1.76-10-5 benzoate ion K, = 6.46 x…

A: According to Bronsted theory greater is the value of Ka of any acid more is the acidity of that…

Q: Draw structures in blank boxes to complete the following reactions. me O₂N mhong Mallo H₂N CI سعد by…

A: Carbocylic acid derivatives undergo nucleophilic substitution reactions

Q: (b) Calculate the pH of 0.0005 mol dm³ ethanoic acid when its pK₁ = 4.75 CH3COOH → CH3COO(+ H* K₁ =…

A: Given, [CH3COOH]=0.0005 mol dm-3 pKa=4.75 pH=?

Q: Name Structure NH; CHCH, 2.20 (CO,H) 9.31 (NH3) 6.3 X 10-3 4.9 x 10-10 Phenylalanine ČO,H 2.148 *…

A: acidic strength of weak carboxylic acids :

Q: 3. Provide structures for all letters (A to K). Write your answers on a separate page BH3ME,S p-TSOH…

A: As the question contains multiple parts. We will only solve first 3 parts of the questions. For the…

Q: Identify the strongest acid. Ka 1.29 x10^-3 (tartaric acid, a component of grapes) O pka = 3.86…

Q: 5) N-Methylbenzylamine CSHIN MW = 121.18 100 120 80 91 60 121 40 77 20 * 9 8 8 8 8 9 messicharge…

Q: Please show arrows for mech. thank you f. он Cu(CH;CN);OTf, TEMPO, air, NMI, bpy Ph OH Ph он РОС,…

Q: NH₂ х CI НО. див ОН SH (1 eq) ОН pyridine ОН P205

A: Detail mechanistic pathway is given below to find out the product

Q: DRAW STRUCTURE V2- 1SOBUYYL -66-diMEtHYL HE PHANOIC ACID 2 (5572)-4-150 PROPYNONA-5,7-0IE NDIC ACIO…

A: We are having names of 3 compound , we have to draw the structure of the given names.

Q: CHs CH Ctes CH3 JUPAC NAME : FUPAC NAME Common name COMMON name: 5.) LURAC NAME Common name A. F) or…

Q: 4. (4а) + NaHCOз — Нао + (4b)_ 5. CH;COOH t CH;CH2OCOCH3 + H20 -COCH3 6. (6а) (6b) - + H2O

A: note: as per our company guidelines, we are supposed to answer Only 1st question at a time. Still I…

Q: H2N -ÇH он CH-OH CH3 a. polar/non-polar; b. Neutral/acidic/basic c. Also write whether the side…

A: For amino acids the polarity of the molecule depends on the functionalities present on the side of…

Q: How do you account for the fact that the -NH3+ group of the conjugate acid of alanine is a stronger…

A: The pKa value of NH3+ group of the conjugate acid of alanine is lower than that of pKa value of NH3+…

Q: 1) CO2 (s) g) Ph(CH2)MgBr 2) 11 (aq) H'(aq/A h) 6-Bromohexanoic Acid + NACN - 1) NaOEt/E:OH i)…

A: Solution: g) Grignard reagent react with co2 in presence of acidic condition corresponding…

Q: (a) . OH محمد (q) HO 0 (d) ت -COH compound?

A: Nuclear magnetic resonance spectroscopy is the branch of chemistry in which we deal with the…

Q: The Ka1 of ascorbic acid is 7.94 x 10-5. Would you expect ascorbic acid dissolved in blood plasma…

A: Given: Ka1= 7.94×10-5pH=7.35-7.45

Q: (p OCH3 OCH3 Pd(OAc)2 Br P(o-tolyl)s Et3N

Q: 1. HN a. polar/non-polar; b. Neutral/acidic/basic c. Also write whether the side chain is…

A: The answers are as follows:

Q: S-OH TSOH HO, acetic acid p-toluenesulfonic acid pKa = 4.8 pK = -7

Q: Biodiesel, a fuel typically derived from plant oils, can be manufactured by treating the oil with a…

A: Biodiesel fuels are an alternative to the diesel fuels, which are much eco-friendly form of fuel.…

Q: HN-CO- Но- HO, ÇI Но- FHO- но- Но CI NHAC H H NH2 N. H H HN HOOC HO ÓH Он HO OH -HO- OH Teicoplanin…

Q: The basic form of the Methyl red (MR-).1 :exhibits a Orange color O Red color O Green color O Yellow…

A: Basic form of methyl red (MR-) is yellow colour

Q: can function as a Léwis acid. O CH2CH2 O CN O Cr(NO3)3 O CH3NH2

A: Lewis acid which gain lone pair of electron

Q: HIN 2. Classify the following compounds as primary, secondary and ter CH2-CH3 CH3 a CH3-CH-NH…

Q: Draw the structures of the intermediates and product of the following reaction.

A: Organic synthesis is a branch of organic chemistry which involves preparation, isolation and…

Q: For each structure on the left, pick an identification on the right. Clear All NH2 (CH)-NH2 amino…

A: The compounds given are,

Q: Classify the following biomolecules given below NH2 Но OH HO-ÇH2 H H OH H H СНО CH3(CH,)22…

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

Which of the following reactions form the product shown on hydrolysis? R=alkyl
HO CH2
co,R
2 CH;MgBr +
CH
HO, CH:
CHLI +
Ph
Ph
OH
O 2 CH;CH MgBr + PhCO,R
= H;CH2C-CH CH3
Ph
periodinane CHO
HO,
CHCI2

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Trending now

This is a popular solution!

Step by step

Solved in 6 steps with 4 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Reaction of hex-3-ene with MCPBA in CH2Cl2 will yield _________. an alkane an alkyne an aldehyde a ketone an epoxide
The following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH. Explain. CH3CO2CH3 > CH3CO2CH2CH3 > CH3CO2CH(CH3)2 > CH3CO2C(CH3)3
Complete the reaction schemes below providing the products of the reaction schemes below.
What products would ypu obtain from reaction of 2,4-dimethyl-2-pentene with BH3, followed by H2O2, OH-? Show its complete reaction mechanism.
Please help with the following... Draw the bond line structured for the reactants and the products obtained in the following reactions: 1. m-tertbutyl benzoic acid + 3-methyl-1butene, HF 2. 3-chloro-2,6-dinitrotulene + sodium ethoxide, ethanol 3. o-methylanisole + isobutanol, BF3
Predict the products of reaction of pent-1-yne with the following reagents. Sia2BH, then H2O2, -OH
5. Predict the product and show the mechanism of the following reaction:(Write out complete equations showing the structure of all reactants and products.) 2-methoxyheptane + Excess conc HBr/heat ----->
The base-promoted rearrangement of an a-haloketone to a carboxylic acid, known as the Favorskii rearrangement, is illustrated by the conversion of 2-chlorocyclohexanone to cyclopentanecarboxylic acid. Jo Han Sow La NaOH, THF O Nat H3O+ OH NaOH, THF The mechanism involves the following 5 steps: -ō cyclopropanone intermediate 1. Abstraction of a proton to form enolate anion 1; 2. Formation of a cyclopropanone intermediate 2 with expulsion of chloride ion; 3. Addition of hydroxide ion to form tetrahedral intermediate 3; 4. Collapse of the tetrahedral intermediate and breakage of the three-membered ring to form carbanion intermediate 4; 5. Proton transfer to form the rearranged carboxylic acid. For the following reaction, draw the reaction out on paper, and then draw the structure of cyclopropanone intermediate 2 in the window. 1. NaOH, THF 2. H3O* OH
Naturally occurring compounds called terpenoids, which we'll discuss in Section 27-5, are biosynthesized by a pathway that involves loss of CO2 from 3-phosphomevalonate 5-diphosphate to yield isopentenyl diphosphate. Use curved arrows to show the mechanism of this reaction.
When certain aromatic compounds are treated with formaldehyde (CH2O), and HCl, the CH2Cl group is introduced onto the ring. This reaction is known as chloromethylation. (a) Propose a mechanism for this example of chloromethylation. (b) The product of this chloromethylation can be converted to piperonal, which is used in perfumery and in artificial cherry and vanilla flavors. How might the CH2Cl group of the chloromethylation product be converted to a CHO group?
Several sulfonylureas, a class of compounds containing RSO2NHCONHR, are useful drugs as orally active replacements for injected insulin in patients with adult-onset diabetes. These drugs decrease blood glucose concentrations by stimulating b cells of the pancreas to release insulin and by increasing the sensitivity of insulin receptors in peripheral tissues to insulin stimulation. Tolbutamide is synthesized by the reaction of the sodium salt of p-toluenesulfonamide and ethyl N-butylcarbamate . Propose a mechanism for this step.
10.3 Complete the following reactions: Show the step-by-step process. Do not use shortcut methods. Make it as detailed as it can be. Encode (not hand-written)!