HSO3¯(aq) + H202(aq) → HSO, (aq) + H20(l) The mechanism is given below, k1 HSO,¯(aq) + H2O2(aq) S so200H¯(aq) + H20(1) k-1 So,00H¯(aq) + H30*(aq) 3 HSO, (aq) + H30*(aq) (fast) k2 a) Which is the reactive intermediate? b) Make a steady-state approximation for the reactive intermediate concentration c) Express the rate of formation of HSO¯439) in terms of the concentrations of HSO¯3(a9), H2O2(39) and H30*(@@

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HSO3¯(aq) + H202(aq) → HSO, (aq) + H20(l)
The mechanism is given below,
k1
HSO3¯(aq)+ H202(aq) S0200H¯(aq) + H20(1l)
k-1
k2
SO200H-(aq) + H30*(aq) 3 HSO, (aq) + H30*(aq) (fast)
a) Which is the reactive intermediate?
b) Make a steady-state approximation for the reactive intermediate concentration
c) Express the rate of formation of HSO 4(a9) in terms of the concentrations of HSO 3(aq),
H2O2(39) and H30*(ag)
Transcribed Image Text:HSO3¯(aq) + H202(aq) → HSO, (aq) + H20(l) The mechanism is given below, k1 HSO3¯(aq)+ H202(aq) S0200H¯(aq) + H20(1l) k-1 k2 SO200H-(aq) + H30*(aq) 3 HSO, (aq) + H30*(aq) (fast) a) Which is the reactive intermediate? b) Make a steady-state approximation for the reactive intermediate concentration c) Express the rate of formation of HSO 4(a9) in terms of the concentrations of HSO 3(aq), H2O2(39) and H30*(ag)
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