Hydrogen is an unusual element because it behaves in someways like the alkali metal elements and in other ways likenonmetals. Its properties can be explained in part by its electronconfiguration and by the values for its ionization energyand electron affinity. (a) Explain why the electron affinity ofhydrogen is much closer to the values for the alkali elementsthan for the halogens. (b) Is the following statement true?“Hydrogen has the smallest bonding atomic radius of anyelement that forms chemical compounds.” If not, correct it.If it is, explain in terms of electron configurations. (c) Explainwhy the ionization energy of hydrogen is closer to the valuesfor the halogens than for the alkali metals. (d) The hydrideion is H-. Write out the process corresponding to the firstionization energy of the hydride ion. (e) How does the processin part (d) compare to the process for the electron affinityof a neutral hydrogen atom?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 75CP
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Hydrogen is an unusual element because it behaves in some
ways like the alkali metal elements and in other ways like
nonmetals. Its properties can be explained in part by its electron
configuration and by the values for its ionization energy
and electron affinity. (a) Explain why the electron affinity of
hydrogen is much closer to the values for the alkali elements
than for the halogens. (b) Is the following statement true?
“Hydrogen has the smallest bonding atomic radius of any
element that forms chemical compounds.” If not, correct it.
If it is, explain in terms of electron configurations. (c) Explain
why the ionization energy of hydrogen is closer to the values
for the halogens than for the alkali metals. (d) The hydride
ion is H-. Write out the process corresponding to the first
ionization energy of the hydride ion. (e) How does the process
in part (d) compare to the process for the electron affinity
of a neutral hydrogen atom?

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