Hydrogen sulfide and oxygen react to form sulfur dioxide and water, like this: 2H₂S(g)+30₂(g) 2SO₂(g)+2H₂O(g) 4 Suppose a mixture of H₂S, O₂, SO₂ and H₂O has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium O to the right The pressure of H₂S will ? to the left Some SO₂ is removed. The pressure of O, will The pressure of H₂S will Some O, is added. The pressure of SO, will ? V V ? ✓? v go up. go down. not change. X O(none) O to the right Oto the left (none) S ?

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Chapter18: Thermodynamics And Equilibrium
Section: Chapter Questions
Problem 18.110QP
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Hydrogen sulfide and oxygen react to form sulfur dioxide and water, like this:
2H₂S(g)+30₂(g)
-
2SO₂(g)+2H₂O(g)
Suppose a mixture of H₂S, O₂, SO₂ and H₂O has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table
below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left.
perturbation
change in composition
shift in equilibrium
O to the right
The pressure of H₂S will
?
Some SO₂ is removed.
to the left
The pressure of O₂ will
(none)
to the right
The pressure of H₂S will
Some 0₂ is added.
The pressure of SO₂ will
?
?
✓ ?
go up.
go down.
not change.
X
Oto the left
O (none)
3
Transcribed Image Text:Hydrogen sulfide and oxygen react to form sulfur dioxide and water, like this: 2H₂S(g)+30₂(g) - 2SO₂(g)+2H₂O(g) Suppose a mixture of H₂S, O₂, SO₂ and H₂O has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium O to the right The pressure of H₂S will ? Some SO₂ is removed. to the left The pressure of O₂ will (none) to the right The pressure of H₂S will Some 0₂ is added. The pressure of SO₂ will ? ? ✓ ? go up. go down. not change. X Oto the left O (none) 3
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