Hydroxyl radicals react with and eliminate many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g)OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g) Use bond energies to explain why this reaction is improbable.
Hydroxyl radicals react with and eliminate many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g)OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g) Use bond energies to explain why this reaction is improbable.
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter5: Principles Of Chemical Reactivity: Energy And Chemical Reactions
Section: Chapter Questions
Problem 69GQ: Use Appendix L to find the standard enthalpies of formation of oxygen atoms, oxygen molecules (O2),...
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Hydroxyl radicals react with and eliminate many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon:
OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g)OH(g)+CF2Cl2(g)→HOF(g)+CFCl2(g)
Use bond energies to explain why this reaction is improbable.
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