Suppose a boil water notice is sent out advising all residents in the area to boil their water before drinking it or using it forcooking. You need to boil 12.0 L of water using your natural gas (primarily methane) stove. What volume of naturalgasisneeded to boil the water if only 19.1% of the heat generated goes towards heating the water. Assume the density of methane is0.668 g/L, the density of water is 1.00 g/mL, and that the water has an initial temperature of 21.3 °C. Enthalpy of formationvalues can be found in this table. Assume that gaseous water is formed in the combustion of methane.549.69volume of methane:LIncorrect

Given: The volume of water, (VH2O) = 12 L = 12000 mL. The initial temperature of the water, (T1) =…

Answered: Suppose a boil water notice is sent out…

World of Chemistry

7th Edition

ISBN:9780618562763

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter10: Energy

Section: Chapter Questions

Problem 65A

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A 110.-g sample of copper (specific heat capacity = 0.20 J/C g) is heated to 82.4C and then placed in a container of water at 22.3C. The final temperature of the water and copper is 24.9C. What is the mass of the water in the container, assuming that all the heat lost by the copper is gained by the water?
9.104 An engineer is using sodium metal as a cooling agent in a design because it has useful thermal properties. Looting up the heat capacity, the engineer finds a value of 28.2 J mol-l °C-l. Carelessly, he wrote this number down without units. As a result, it was later taken as specific heat. (a) What would he the difference between these two values? (b) Would the engineer overestimate the ability of sodium to remove heat from the system or underestimate it because of this error? Be sure to explain your reasoning.
If a reaction produces 1.506 kJ of heat, which is trapped in 30.0 g of water initially at 26.5 °C in a calorimeter like that in Figure 5.12, what is the resulting temperature of the water?
9.90 Many engineering designs must incorporate ways to dissipate energy in the form of heat. Water evaporators are common for this task. (a) What property of water makes it a good material for evaporators? {b} If an application could not use water, hut instead was forced to use a material with a value for the property in part (a) that was one half that of water, what changes would need to be made in the design?
9.97 Suppose that the working fluid inside an industrial refrigerator absorbs 680 J of energy for every gram of material that vaporizes in the evaporator. The refrigerator unit uses this energy flow as part of a cyclic system to keep foods cold. A new pallet of fruit with a mass of 500 kg is placed in the refrigerator. Assume that the specific heat of the fruit is the same as that of pure water because the fruit is mostly water. Describe how you would determine the mass of the working fluid that would have to be evaporated to lower the temperature of the fruit by 15C. List any information you would have to measure or look up.
The “Chemistry in Focus” segment Nature Has Hot Plants discusses thermogenic, or heat-producing, plants. For some plants, enough heat is generated to increase the temperature of the blossom by 15 °C. About how much heat is required to increase the temperature of 1 L of water by 15 °C?
Hydrogen is an ideal fuel in many respects; for example, the product of its combustion, water, is nonpolluting. The heat given off in burning hydrogen to gaseous water is 5.16 104 Btu per pound. What is this heat energy in joules per gram? (1 Btu = 252 cal; see also Table 1.4.)
In the “Chemistry in Focus” segment Firewalking: Magic or Science?, it is claimed that one reason people can walk on hot coals is that human tissue is mainly composed of water. Because of this, a large amount of heat must be transferred from the coals to change the temperature of the feet significantly. How much heat must be transferred to 100.0 g of water to change its temperature by 35 °C?
A piece of chocolate cake contains about 400 calories. A nutritional calorie is equal to 1000 calories (thermochemical calories), which is equal to 4.184 kJ. How many 8-in-high steps must a 180-lb man climb to expend the 400 Cal from the piece of cake? See Exercise 28 for the formula for potential energy.
Enthalpy a A 100.-g sample of water is placed in an insulated container and allowed to come to room temperature at 21C. To heat the water sample to 41C, how much heat must you add to it? b Consider the hypothetical reaction,2X(aq)+Y(l)X2Y(aq)being run in an insulated container that contains 100. g of solution. If the temperature of the solution changes from 21C to 31C, how much heat does the chemical reaction produce? How does this answer compare with that in part a? (You can assume that this solution is so dilute that it has the same heat capacity as pure water.) c If you wanted the temperature of 100. g of this solution to increase from 21C to 51C, how much heat would you have to add to it? (Try to answer this question without using a formula.) d If you had added 0.02 mol of X and 0.01 mol of Y to form the solution in part b, how many moles of X and Y would you need to bring about the temperature change described in part c. e Judging on the basis of your answers so far, what is the enthalpy of the reaction 2X(aq) + Y(l) X2Y(aq)?
A 45-g aluminum spoon (specific heat 0.88 J/g C) at 24 C is placed in 180 mL (180 g) of coffee at 85 C and the temperature of the two become equal. (a) What is the final temperature when the two become equal? Assume that coffee has the same specific heat as water. (b) The first time a student solved this problem she got an answer of 88 C. Explain why this is clearly an incorrect answer.
If 125 J of heat energy is applied to a block of silver weighing 29.3 g, by how many degrees will the temperature of the silver increase? (See Table 10.1.)

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