I am stuck with deriving these two equations in the far right corner in the box. i reached this far and can't seem to understand the next step moving foward. can you please derive the two equations from eqn 1,2 and 3. These are absorbance equation used in experimental determination of

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter9: Atomic Absorption And Atomic Fluorescence Spectrometry
Section: Chapter Questions
Problem 9.23QAP
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The rotational constant B. can be determined hy theasilih..
Derned
Formul a
Porms
[aro V];- Az-Ai LAo
%3D
A2- Ai
Comp ounds
Sol1:
= Earo t CAro Hy
Ern 2
ニ
A2-A
Ac LEAroH I Aro 4]
Earolt=
Ai
[AroHIo
soln a:
A= EACO [Aro]
7n 3
EAro = Aa
if A
EAroH LAroH]+
Ear o IAio]
Earot
then
A- Earob CArouto t EAro I Aro 3.
Ai= Ai
Transcribed Image Text:The rotational constant B. can be determined hy theasilih.. Derned Formul a Porms [aro V];- Az-Ai LAo %3D A2- Ai Comp ounds Sol1: = Earo t CAro Hy Ern 2 ニ A2-A Ac LEAroH I Aro 4] Earolt= Ai [AroHIo soln a: A= EACO [Aro] 7n 3 EAro = Aa if A EAroH LAroH]+ Ear o IAio] Earot then A- Earob CArouto t EAro I Aro 3. Ai= Ai
I am stuck with deriving these two equations in the far right
corner in the box. i reached this far and can't seem to
understand the next step moving foward. can you please
derive the two equations from eqn 1,2 and 3. These are
absorbance equation used in experimental determination of
2-Naphthol excited state PKa. The purpose of the formula
is to find the unknown concentration of ArOH and its
conjugate base in the solution given absorbance data.
Transcribed Image Text:I am stuck with deriving these two equations in the far right corner in the box. i reached this far and can't seem to understand the next step moving foward. can you please derive the two equations from eqn 1,2 and 3. These are absorbance equation used in experimental determination of 2-Naphthol excited state PKa. The purpose of the formula is to find the unknown concentration of ArOH and its conjugate base in the solution given absorbance data.
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