Answered: (i) the total pressure inside the…

(i) the total pressure inside the vessel once equilibrium is reached; (ii) the mass of CaCO3 if the container is compressed until its volume is 7.00 L, and equilib- rium is reached.

General Chemistry - Standalone book (MindTap Course List)

11th Edition

ISBN:9781305580343

Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Chapter14: Chemical Equilibirum

Section14.2: The Equilibrium Constant

Problem 14.3E: When 1.00 mol each of carbon monoxide and water reach equilibrium at 1000C in a 10.0-L vessel, the...

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Question

Exercise 5
80.0 g of CaCO3 are placed inside a 10.0 L empty vessel. The temperature is then raised to
1200 K and the equilibrium below is established. Using the provided thermodynamic data,
calculate the following:
(i) the total pressure inside the vessel once equilibrium is reached;
(ii) the mass of CaCO3 if the container is compressed until its volume is 7.00 L, and equilib-
rium is reached.
CaCO3(s) = CaO(s) + CO₂(g)
AƒH (kJ mol-1¹) S (Jmol-¹K¯¹)
-1206.9
CaCO3(s)
CaO(s)
CO₂(g)
Answer: (i) 4.63 atm, (ii) 47.0 g
-635.5
-393.5
93
40
214

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