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- A powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr.What is the %purity of the sample to the nearest whole number?The mercury in a 0.8142-g sample was precipitated with an excess of paraperiodic acid, H5IO6: 5 Hg 2+ + 2 H5IO6 ---> Hg5(IO6)2 (s) + 10 H + The precipitate (MW = 1448.8 g/mol) was filtered, washed free of precipitating agent, dried, and weighed, and 0.4114 g was recovered. Calculate the a) % Hg (200.6 g/mol) b) % Hg2Cl2 (472.1 g/mol)Souring of wine occurs when ethanol is converted to acetic acid by oxygen: C2H5OH(l) +O2(g)--->CH3COOH(g)+H2O(l). A 1.00 L bottle of wine labeled as 7.00% (%v/v) ethanol, is found to have a defective seal. Analysis of 1.00 mL showed that there were 0.0274 g acetic acid in that 1.00 mL. The density of ethanol is 0.816 g/mL. (a) What mass of oxygen must leaked into the bottle in pounds(lb) (b) What is the percent yield for the conversion of ethanol to acetic acid, if oxygen is in excess
- What is the density of 47.0 wt% aqueous NaOH (FM 40.00) if 17.6 mL of the solution diluted to 1.80 L give 0.172 M NaOH?A weight of 0.50 g was taken impure container containing sodium carbonate and bicarbonate. Dissolved in water and then crushed with hydrochloric acid (0.1 N), the burette reading game was at the endpoint of phenolphthalein of 10.5 ml and at the end point of the orange methylation point 30.1 ml. The percentage of sodium carbonate was in ................. knowing that the weights are: Na: 23, C: 12, O: 16Determine the percentage Fe in a sample of limonite from the following data:Sample : 0.5000g ; KMnO4 used = 50.00 ml ; 1.000ml of KMnO4 is equivalent 0.005317 g Fe,FeSO4 used = 6.00 ml; 1.000ml FeSO4 is equivalent 0.009200 g FeO ( ans 44.59 %)
- Organic carbon in seawater can be measured by oxidation to CO2 with K2S2O8, followed by gravimetric determina- tion of CO2 trapped by a column of Ascarite. Water weighing 6.234 g produced 2.378 mg of CO2 (FM 44.010). Find ppm carbon in the seawater.To a 0.5 g sample of impure NaCl are added 0.784 g of pure AgNO3 (MW = 169.88) crystal. This is in excess of the amount required to ppt. All the Cl as AgCl. After dissolving and filtering out the pptd. AgCl, the filtrate requires 25.50 ml of 0.028M KCNS. What is the percentage of NaCl (MW=58.44) in the sample? A. 55.40 % B. 50.10% C. 45.60% D. 100%The water in Fell city also contains 30 μg/L of chloroform (formed in the water treatment plant), 5 μg/L of chlorpyriphos (a persticide), and 10 μg/L of chromium VI. Given the reference doses below, calculate the total hazard quotient. State which compound is the total HQ is acceptable. References doses (all mg/kg.d): 0.01 for chloroform, 0.0003 for chlorpyiphos, and 0.003 for chromium VI. Answer: 0.66
- An impure sample of Na3PO3 weighing 0.1 g is dissolved in 35 mL of water. A solution containing 45 mL of 3% w/v HgCl2, 30 mL of 10% w/v sodium acetate, and 10 mL of glacial acetic acid is then prepared. After digesting, filtering, and rinsing the precipitate, 0.2857 g of Hg2Cl2 is obtained. Report the purity of the original sample as % w/w Na3PO3.A (3.6500 g) of impure ammonium aluminium sulfate (NH4Al(SO4)2)) was treated with ammonia (NH3(aq)) producing hydrous alumina Al2O3.xH2O. The collected precipitate was filtered, washed, and ignited at 1000 °C to give 0.4935 g Al2O3 (Mw 101.9635 g/mol). Determine: a. % Al2O3 b. %Al c. Express concentration of Al in ppm.One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
