If the equilibrium constant, Keq, for the conversion of isobutene to n-butane is 2.5, what is the value of the equilibrium constant for the reverse reaction? a. 2.5 e. 1.0 b. 0.4 c. 6.25 d. 1.3
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- For the exothermic reaction PCl3(g)+Cl2(g)⇌PCl5(g)PCl3(g)+Cl2(g)⇌PCl5(g) K = 0.200 at a certain temperature. A flask is charged with 0.507 bar PCl3 , 0.507 bar Cl2, and 0.304 bar PCl5 at this temperature. What are the equilibrium partial pressures of PCl3, Cl2, and PCl5, respectively?For the exothermic reaction: PCl3(g)+Cl2(g)⇌PCl5(g) K = 0.120 at a certain temperature. A flask is charged with 0.507 bar PCl3, 0.507 bar Cl2, and 0.304 bar PCl5 at this temperature. What are the equilibrium partial pressures of PCl3 , Cl2, and PCl5?For the reaction COCl2g(?) ↔ ?o (?) + ?l22(?), Kp was experimentally determined to be 0.0444 at 394.8 °C. assume that initially, n moles of COCl2(g) and no moles of CO(g) and Cl2(g) are present.a) Find the partial pressures of CO (g) and Cl2 (g) at equilibrium given 1.00 bar total pressure.b) What is the value of ∆rG at equilibrium?c) Determine ∆?G using the given equilibrium constant K.
- Consider the reaction: CO2(g) + H2(g) + CO(g) + H2O(g), for which Kc = 0.64 at 900 K. If the initial CO2 and of H2 are each 0.100 M, what will be the equilibrium concentrations of each species after the reaction reaches equilibrium? A. (CO2] = 0.044 M; [H2] = 0.044M; [CO] = 0.056 M; [H2O) = 0.056 M B. (CO2) = 0.056 M; [H2] = 0.056 M; [CO] = 0.044 M; [H2O) = 0.044 M C. [CO2] = 0.020 M; [H2] = 0.020 M; [CO] = 0.080 M; [H0] = 0.080 M D. [CO2] = 0.080 M; [H2] = 0.080 M; [CO] = 0.020 M; [H2O] = 0.020 M E. None of these.Consider the following reaction:????(?) + ??(?) ⇌ ???(?) + ???(?) 1.1 Determine the estimated value of the equilibrium constant for this reaction at 200 `C by making use of the following data: Is the reaction reactant- or product favoured atthis temperature? Use a short sentence to explain your answer. Substance ?° (????. ?) ?? ?? ? ∆??° (?? ???) ?? ??° Cu2S(?) 120.9 -79.5 O2(?) 205.0 0 Cu(s) 33.1 0 SO2(g) 248.1 -296.8Consider the reaction. 2A(g)↽−−⇀B(g) ?p=3.70×10−5 at 500 K2A(g)↽−−⇀B(g) Kp=3.70×10−5at 500 K If a sample of A(g)A(g) at 3.40 atm3.40 atm is heated to 500 K,500 K, what is the pressure of B(g)B(g) at equilibrium? ?B=PB= atm
- 7.1(b) For the equilibrium, N2O4(g) 5 2 NO2(g), the degree of dissociation, αe, at 298 K is 0.201 at 1.00 bar total pressure. Calculate (a) ∆r G, (2) K, and (3) ∆r G7 at 298 K.Nitrogen and oxygen react at high temperatures. (a) Write the expression for the equilibrium constant (Kc) for the reversible reactionN2(?)+O2(?)⇌2NO(?)Δ?=181kJN2(g)+O2(g)⇌2NO(g)ΔH=181kJ (b) What will happen to the concentrations of N2, O2, and NO at equilibrium if more O2 is added? (c) What will happen to the concentrations of N2, O2, and NO at equilibrium if N2 is removed? (d) What will happen to the concentrations of N2, O2, and NO at equilibrium if NO is added? (e) What will happen to the concentrations of N2, O2, and NO at equilibrium if the volume of the reaction vessel is decreased? (f) What will happen to the concentrations of N2, O2, and NO at equilibrium if the temperature of the system is increased?Methanol 1CH3OH2 is produced commercially by thecatalyzed reaction of carbon monoxide and hydrogen:CO1g2 + 2 H21g2 ∆ CH3OH1g2. An equilibrium mixture in a 2.00-L vessel is found to contain 0.0406 molCH3OH, 0.170 mol CO, and 0.302 mol H2 at 500 K. Calculate Kc at this temperature.
- Consider the reaction. 2A(g)↽−−⇀B(g) ?p=3.70×10−5 at 500 K2A(g)↽−−⇀B(g) Kp=3.70×10−5at 500 K If a sample of A(g)A(g) at 3.40 atm3.40 atm is heated to 500 K,500 K, what is the pressure of B(g)B(g) at equilibrium? ?B=PB= atm The ANSWER IS NOT 6.756*10 ^-4Consider the reaction NH4HS(s)⇌NH3(g)+H2S(g)NH4HS(s)⇌NH3(g)+H2S(g) At a certain temperature, Kc=8.5×10−3�c=8.5×10−3. A reaction mixture at this temperature containing solid NH4HSNH4HS has [NH3]=0.0887M[NH3]=0.0887� and [H2S]=0.0887M[H2S]=0.0887�.Calculate the reaction quotient (Q)(�).7.4(b) In the gas-phase reaction A + B 5 C + 2 D, it was found that, when 2.00 mol A, 1.00 mol B, and 3.00 mol D were mixed and allowed to come to equilibrium at 25°C, the resulting mixture contained 0.79 mol C at a total pressure of 1.00 bar. Calculate (a) the mole fractions of each species at equilibrium, (b) Kx, (c) K, and (d) ∆r G7 .