iii) Upon cooling the filtrate from step il, some tiny crystals appear in the filtrate. Addition of a few drops 1M K₂CrO₂ produces a yellow precipitate confirms the presence of: O Ag Pb2+ Pb2 and Hg₂ O Hg2+
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- A first-stage recovery of magnesium from seawater is precipitationof Mg1OH22 with CaO:Mg2+(aq) + CaO(s) + H2O(l)---->Mg(OH)2(s) + Ca2+(aq) What mass of CaO, in grams, is needed to precipitate 1000lb of Mg(OH)2?1. A newly discovered iron ore was weighted (5.408 g) and worked up to produced 0.3785 g of ignited Fe2O3 precipitate. What is the percent purity of the iron in the sample? 2. Distinguish between equivalence point and end point.A sample of an iron ore was prepared for Fe3+ analysis as following: 3.4g of the sample was added anddissolved in acid environment then diluted to 250 mL using volumetric flask. After that, 10 mL of the resultingsolution was transferred by pipet to a 50-mL volumetric flask and continue to be diluted. The scientists foundout that this solution gives the concentration of Fe3+ as 2.3 mg/L. Find the weight percentage of Fe3+ in theoriginal sample.
- Ferric oxide (Fe2O3, density 5 5.24 g/mL) obtained from ignition of a gravimetric precipitate weighed 0.296 1 g in the atmosphere. What is the true mass in vacuum?4. determine the amount in mg of the amount of Ag present from ICP mass digested: 1.0821g/L dilution of 10ml stock solution to 100ml volumetric flask X=0.98 (intensity)A 25.0 cm portion of 0.200, mol dm^-3 sodium ethanedioate solution was warmed and titrated against a solution of potassium manganate(VII). If 17.2 cm^3 of potassium manganate(VII) are required, what is its concentration?
- What is the purpose of acetone in the final filtration of the precipitate in Gravimetric Determination of Calcium as CaC2O4·H2O?A 1.000-gram sample of NaOH (39.997 g/mol) which has been exposed to the air for some time (NaOH will adsorb water and CO2 from the ambient air) is dissolved in water and then diluted to 500.00 mL. 100.0 mL of this solution required 38.60 mL of 0.1062 M HCl to be titrated to the endpoint (~pH 3). A second 100.00 mL portion is treated with excess BaCl2 and then diluted to 250 mL and filtered. 200 mL of the filtrate required 29.62 mL of HCl to titrate to the (~pH 8-9) endpoint. Calculate the mass percentage of NaOH and Na2CO3 (105.9898 g/mol) in the original sample. The adsorbed CO2 is converted to Na2CO3. The Ksp for BaCO3 (s) is 2.58 x 10-9.A 0.4020 g sample was dissolved, and Ca2+ and Ba2+ ions present were precipitated as Ba.C2O4.H2O and CaC2O4H2O. The Oxalates were then heated in a thermogravimetric apparatus leaving a residue that weighed 0.3175 g in the range of 320°C to 440°C and 0.2165 g in the range of 580°C to 620°C. Calculate percentage Ca and percentage Ba in the sample.
- A 500.0mg of butter was warmed and shaken vigorously with water. The undissolved material was removed by filtering and the aqueous portion was made 1.0M in HNO3 and 0.025M in Fe(NO3)3. This acidified solution was treated with 10.00ml of 0.1755M AgNO3 to precipitate the chloride ion and, after the addition of a small amount of nitrobenzene, 14.22ml of 0.1006M KSCN was required to back titrated the excess Ag+. Calculate the % NaCl in the butter.The concentration of ammonia in a cleaning product was determined by back titration.Firstly, 10.00 cm3 of the cleaning product was pipetted into a large conical flask,containing 250.00cm3 of 0.50 mol/l HCl to give Solution A.Following a period of reaction and shaking, 50.00cm3 of Solution A was removed anddiluted to 250 cm3 with water in a volumetric flask to give Solution B.20 cm3 samples of Solution B were titrated against 0.05 mol/l Na2CO3 solution, givingan average titre of 12.45 cm3. i) Write equations for the reactions that have taken place.ii) Determine the concentration of NH3 in the original cleaning product in mol/l,g/l, ppm, and % w/v.To a 0.5 g sample of impure NaCl are added 0.784 g of pure AgNO3 (MW = 169.88) crystal. This is in excess of the amount required to ppt. All the Cl as AgCl. After dissolving and filtering out the pptd. AgCl, the filtrate requires 25.50 ml of 0.28M KCNS. What is the percentage of NaCl (MW=58.44) in the sample?