In a free-radical polymerization that proceeds in the absence of chain transfer, what would be the effect of (a) increasing the monomer concentration [M] four times at constant initiator concentration [I] and (b) increasing [I] four times at constant [M] upon (i) the total radical concentration at steady state, (ii) the rate of polymerization, and (iii) the number-average degree of polymerization

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter32: Radiochemical Methods
Section: Chapter Questions
Problem 32.13QAP
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In a free-radical polymerization that proceeds in the absence of chain transfer, what would be the effect of (a) increasing the monomer concentration [M] four times at constant initiator concentration [I] and (b) increasing [I] four times at constant [M] upon (i) the total radical concentration at steady state, (ii) the rate of polymerization, and (iii) the number-average degree of polymerization  
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