In a galvanic cell, one half-cell consists of gaseous chlorine bubbled over a platinum electrode at a pressure of 1.00 atm into a 1.00 M solution of NaCl. The second half-cell has a strip of solid gallium immersed in a 1.00 M Ga(NO3)3 solution. The initial cell potential is measured to be 1.918 V at25°C, and as the cell operates, the concentration of chloride ion is observed to increase.(a) Write balanced equations for the half-reactions at the anode and the cathode.(b) Calculate the standard reduction potential of a Ga3+ | Ga half-cell. Consult Appendix E for the reduction potential of the Cl2 | Cl- electrode

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.49QE: A half-cell that consists of a copper wire in a 1.00 M Cu(NO3)2 solution is connected by a salt...
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In a galvanic cell, one half-cell consists of gaseous chlorine bubbled over a platinum electrode at a pressure of 1.00 atm into a 1.00 M solution of NaCl. The second half-cell has a strip of solid gallium immersed in a 1.00 M Ga(NO3)3 solution. The initial cell potential is measured to be 1.918 V at
25°C, and as the cell operates, the concentration of chloride ion is observed to increase.
(a) Write balanced equations for the half-reactions at the anode and the cathode.
(b) Calculate the standard reduction potential of a Ga3+ | Ga half-cell. Consult Appendix E for the reduction potential of the Cl2 | Cl- electrode

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