In a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH31/2 N,+3/2 H2 the concentration of NH, was followed as a function of time. It was found that a graph of [NH3] versus time in seconds gave a straight line with a slope of -4.52x10-6 M s and a y-intercept of 5.82×10³ M. Based on this plot, the reaction is order in NHz and the rate constant for the reaction is Ms.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.1: Reaction Rate
Problem 11.3CE
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In a study of the decomposition of ammonia on a tungsten surface at 1100 °C
NH3-
→1/2 N2 + 3/2 H,
the concentration of NH3 was followed as a function of time.
It was found that a graph of [NH3] versus time in seconds gave a straight line with a slope of
-4.52x10-6 M s1 and a y-intercept of 5.82×10-3 M.
Based on this plot, the reaction is
order in NH, and the rate constant for the reaction is
Ms!.
Transcribed Image Text:In a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH3- →1/2 N2 + 3/2 H, the concentration of NH3 was followed as a function of time. It was found that a graph of [NH3] versus time in seconds gave a straight line with a slope of -4.52x10-6 M s1 and a y-intercept of 5.82×10-3 M. Based on this plot, the reaction is order in NH, and the rate constant for the reaction is Ms!.
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