In a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g) 2 H2(g) + ½ I2(g) the following data were obtained: [HI], M seconds 1.48 0.740 0.370 0.185 750 2.25x103 5.25x103 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 1.48 M is 750 the starting concentration is 0.740 M is 1500 s and when S. (2) The average A(1/[HI]) / At from t = 0 s to t = 750 s is M-1 s-1. The average A(1/[HI]) / At from t = 750 s to t = 2.25×10³ s is M-1 s-1. (3) Based on these data, the rate constant for this e order reaction is M-1 s-1.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
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In a study of the gas phase decomposition of hydrogen iodide at 700 K
HI(g)-
→½ H2(g) + ½ I2(g)
the following data were obtained:
[HI], M
seconds
1.48
0.740
0.370
0.185
750
2.25x103
5.25x103
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 1.48 M is 750
s and when
the starting concentration is 0.740 M is 1500
S.
(2)
The average A(1/[HI]) / At from t = 0 s to t = 750 s is
M-1 s-1.
The average A(1/[HI]) / At from t
750 s to t = 2.25×103 s is
M-1 s-1.
(3)
Based on these data, the rate constant for this
0 order reaction is
M-1 s-1.
Transcribed Image Text:In a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g)- →½ H2(g) + ½ I2(g) the following data were obtained: [HI], M seconds 1.48 0.740 0.370 0.185 750 2.25x103 5.25x103 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 1.48 M is 750 s and when the starting concentration is 0.740 M is 1500 S. (2) The average A(1/[HI]) / At from t = 0 s to t = 750 s is M-1 s-1. The average A(1/[HI]) / At from t 750 s to t = 2.25×103 s is M-1 s-1. (3) Based on these data, the rate constant for this 0 order reaction is M-1 s-1.
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