In the expanded region of 1H NMR for 4-t-butylcyclohexanols, the peak at 4.05 ppm integrates to 1.0 while the peak at 3.52 ppm integrates to 2.52. Please use this information to calculate the percentage of each isomer in the sample. QUESTION- Based on the 1H NMR, Please explain the cis vs. trans product ratio. Is it consistent with the expected results? Why or why not? HO4.05х1.007.5HO807.0H C756.5CH₂CH371.1270отCH33.706.065.8065смимedhinтамирније3.65 3.60 3.55 3.50 3.45 3.405.5CH3602.52555.0504.547.2148 07454.0401.03.50.936.07350.83.033.4032.27302.527.6625.64252.020.93201.5151.0100.55----0.00-5 NMR SpectraThe 'H and ¹3C NMR spectra of 4-t-butylcyclohexanone, your starting material, are shownbelow. The ¹H NMR of your product is shown next with the resonances from 3 to 5 ppmexpanded so you can see them in detail and integrated. About the only useful absorption is thesinglet that integrates to 9. The ketone carbonyl is visible at 212 ppm in the ¹3C NMR spectrum13,however.Ar7.57.0212.366.5200CH3FCH36.05.5CH3-CH3CH3-CH35.01504.54.03.51003.06.222.52.03.04501.541.3146.719.0032.461.027.610.50ון0.0

“Since you have asked multiple questions, we will solve the first question for you. If you want any…

Answered: In the expanded region of 1H NMR for…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Concept explainers

Question

100%

In the expanded region of ¹H NMR for 4-t-butylcyclohexanols, the peak at 4.05 ppm integrates to 1.0 while the peak at 3.52 ppm integrates to 2.52. Please use this information to calculate the percentage of each isomer in the sample.

QUESTION- Based on the 1H NMR, Please explain the cis vs. trans product ratio. Is it consistent with the expected results? Why or why not?

HO
4.05
х
1.00
7.5
HO
80
7.0
H C
75
6.5
CH₂
CH3
71.12
70
от
CH3
3.70
6.0
65.80
65
смим
edhin
тамирније
3.65 3.60 3.55 3.50 3.45 3.40
5.5
CH3
60
2.52
55
5.0
50
4.5
47.21
48 07
45
4.0
40
1.0
3.5
0.9
36.07
35
0.8
3.0
33.40
32.27
30
2.5
27.66
25.64
25
2.0
20.93
20
1.5
15
1.0
10
0.5
5
----
0.0
0
-5

NMR Spectra
The 'H and ¹3C NMR spectra of 4-t-butylcyclohexanone, your starting material, are shown
below. The ¹H NMR of your product is shown next with the resonances from 3 to 5 ppm
expanded so you can see them in detail and integrated. About the only useful absorption is the
singlet that integrates to 9. The ketone carbonyl is visible at 212 ppm in the ¹3C NMR spectrum
13,
however.
Ar
7.5
7.0
212.36
6.5
200
CH3
F
CH3
6.0
5.5
CH3
-CH3
CH3
-CH3
5.0
150
4.5
4.0
3.5
100
3.0
6.22
2.5
2.0
3.04
50
1.5
41.31
46.71
9.00
32.46
1.0
27.61
0.5
0
ון
0.0

Expert Solution

Step by step

Solved in 3 steps with 6 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions