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- why doesn't F22+ occur (with respect to molecular orbital theory)? illustrate as needed.Study MFT370, Fig.10.8. Infer the molecular orbital energy level diagram of the CN- ion by sketching the overlap of all the relevant atomic orbitals.Indicate which operation is equivalent to the following products for the Td point group S4×S4=? C3×C2=? σd×C2=?
- Is delocalization possible in Hydrogen selenate (HOSeO3- )Which does not demostrate a pi electron delocalization?Chemistry Draw the new Molecular orbital energy diagram for [Co(NH3)5(H2O)]3+, indicating the symmetrydesignations for the orbitals. You have to go through the reduciblerepresentation process
- The FEMO theory of conjugated molecules is crude and marginally better results are obtained with simple Huckel theory. (a) For a linear conjugated polyene with each of N carbon atoms contributing an electron in a 2porbital, the energies Ek of the resulting π molecular orbitals are given by: Ek = α + 2β cos kπ/N+1 k = 1,2,3, ... N Use this expression to estimate the resonance integral β for the series consisting of ethene, butadiene, hexatriene, and octatetraene given that ult raviolet absorptions from the HOMO, which is a bonding π orbital, to the LUMO, which is an antibonding π* orbital, occur at 61 500, 46 080, 39 750,and 32 900 cm- 1, respectively. (b) Calculate the π-electron delocalization energy, Edelcc = Eπ -n(α + β). of octatetraene, where Eπ, is the total π-electron binding energy and n is the total number of π-electrons.If [CH4}) = 0.1M; [O2] = 0.25M\[CO2 ]= 0.35M and [H2O] = 0.15M what is the value of Qc?Using molecular orbital theory, why doesn't F22+ occur even though it has a bond order of 2? Provide an explanation and illustrate if needed.